Abstract
In the title compound, [Cd(C 10H 6NO 2) 2] n , the Cd II atom is coordinated by three O atoms and two N atoms from four quinoline-3-carboxyl-ate (L -) ligands, leading to a distorted trigonal-bipyramidal geometry. The L - ligands link the Cd II atoms into a plane parallel to (100), with one ligand being tridentate, coordinating via the N atom and chelating a second Cd atom, and the other being bidentate, bridging two Cd atoms via the N and one O atom.. This two-dimensional network extends into a double-layer network by π-π inter-actions, with centroid-centroid distances of 3.680 (2) and 3.752 (2) Å. Another type of π-π inter-action between pyridine rings [centroid-centroid distance = 3.527 (2) Å] leads to a three-dimensional supra-molecular architecture.
| Original language | English |
|---|---|
| Pages (from-to) | m163 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 68 |
| Issue number | 2 |
| DOIs | |
| State | Published - Feb 2012 |
| Externally published | Yes |
Keywords
- R factor = 0.019
- T = 153 K
- data-to-parameter ratio = 12.4
- mean σ(C-C) = 0.003 Å
- single-crystal X-ray study
- wR factor = 0.051
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