Photoelectron spectroscopy study of orbital interactions. Ethynylfurans

Igor Novak; Siu Choon Ng; Shengxi Jin; Hsing Hua Huang; Wei Huang

doi:10.1021/jp963901w

Photoelectron spectroscopy study of orbital interactions. Ethynylfurans

Igor Novak
, Siu Choon Ng
, Shengxi Jin
, Hsing Hua Huang
, Wei Huang

National University of Singapore

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

He I and He II photoelectron spectra (UPS) of isomeric mono- and bis(ethynyl)furans were recorded. The assignment of spectra was based on empirical considerations (bandwidths, He II/He I intensity variations, comparison with spectra of related molecules) and ab initio calculations. The details of orbital interactions between the ring and ethynyl π orbitals were deduced solely on the basis of experimental data. These interactions were studied for several classes of π isoelectronic molecules.

Original language	English
Pages (from-to)	3501-3504
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	101
Issue number	19
DOIs	https://doi.org/10.1021/jp963901w
State	Published - 8 May 1997
Externally published	Yes

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10.1021/jp963901w

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title = "Photoelectron spectroscopy study of orbital interactions. Ethynylfurans",

abstract = "He I and He II photoelectron spectra (UPS) of isomeric mono- and bis(ethynyl)furans were recorded. The assignment of spectra was based on empirical considerations (bandwidths, He II/He I intensity variations, comparison with spectra of related molecules) and ab initio calculations. The details of orbital interactions between the ring and ethynyl π orbitals were deduced solely on the basis of experimental data. These interactions were studied for several classes of π isoelectronic molecules.",

author = "Igor Novak and Ng, \{Siu Choon\} and Shengxi Jin and Huang, \{Hsing Hua\} and Wei Huang",

year = "1997",

month = may,

day = "8",

doi = "10.1021/jp963901w",

language = "英语",

volume = "101",

pages = "3501--3504",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

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TY - JOUR

T1 - Photoelectron spectroscopy study of orbital interactions. Ethynylfurans

AU - Novak, Igor

AU - Ng, Siu Choon

AU - Jin, Shengxi

AU - Huang, Hsing Hua

AU - Huang, Wei

PY - 1997/5/8

Y1 - 1997/5/8

N2 - He I and He II photoelectron spectra (UPS) of isomeric mono- and bis(ethynyl)furans were recorded. The assignment of spectra was based on empirical considerations (bandwidths, He II/He I intensity variations, comparison with spectra of related molecules) and ab initio calculations. The details of orbital interactions between the ring and ethynyl π orbitals were deduced solely on the basis of experimental data. These interactions were studied for several classes of π isoelectronic molecules.

AB - He I and He II photoelectron spectra (UPS) of isomeric mono- and bis(ethynyl)furans were recorded. The assignment of spectra was based on empirical considerations (bandwidths, He II/He I intensity variations, comparison with spectra of related molecules) and ab initio calculations. The details of orbital interactions between the ring and ethynyl π orbitals were deduced solely on the basis of experimental data. These interactions were studied for several classes of π isoelectronic molecules.

UR - https://www.scopus.com/pages/publications/0011816469

U2 - 10.1021/jp963901w

DO - 10.1021/jp963901w

M3 - 文章

AN - SCOPUS:0011816469

SN - 1089-5639

VL - 101

SP - 3501

EP - 3504

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 19

ER -

Photoelectron spectroscopy study of orbital interactions. Ethynylfurans

Abstract

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