Pd(OAc)2/CuI-Catalyzed Tandem Reaction for Synthesis of Polysubstituted 3-Chalcogenylindoles

Ruiting Liu; Zhen Li; Shengke Wang; Xigeng Zhou

doi:10.6023/cjoc201904032

Pd(OAc)₂/CuI-Catalyzed Tandem Reaction for Synthesis of Polysubstituted 3-Chalcogenylindoles

Ruiting Liu
, Zhen Li
, Shengke Wang
, Xigeng Zhou

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Tandem Pd(OAc)₂/CuI catalyzed coupling/cyclization/chalcogenylation reaction of gem-dibromovinylanilines with boronic acids and dichalcogenides has been developed, which provides a new synthetic approach to 3-sulfenyl- and 3-selenylindoles. Various functional groups such as methoxyl, halides and trifluoromethyl groups in the substrates are tolerated.

Translated title of the contribution	Pd(OAc)₂/CuI分步催化合成多取代3-烃硫(硒)基吲哚化合物
Original language	English
Pages (from-to)	3215-3222
Number of pages	8
Journal	Chinese Journal of Organic Chemistry
Volume	39
Issue number	11
DOIs	https://doi.org/10.6023/cjoc201904032
State	Published - 1 Nov 2019
Externally published	Yes

Keywords

Catalysis
Indole
Pd(OAc)/CuI
Synthesis

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title = "Pd(OAc)2/CuI-Catalyzed Tandem Reaction for Synthesis of Polysubstituted 3-Chalcogenylindoles",

abstract = "Tandem Pd(OAc)2/CuI catalyzed coupling/cyclization/chalcogenylation reaction of gem-dibromovinylanilines with boronic acids and dichalcogenides has been developed, which provides a new synthetic approach to 3-sulfenyl- and 3-selenylindoles. Various functional groups such as methoxyl, halides and trifluoromethyl groups in the substrates are tolerated.",

keywords = "Catalysis, Indole, Pd(OAc)/CuI, Synthesis",

author = "Ruiting Liu and Zhen Li and Shengke Wang and Xigeng Zhou",

note = "Publisher Copyright: {\textcopyright} 2019 Chinese Chemical Society \& SIOC, CAS.",

year = "2019",

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doi = "10.6023/cjoc201904032",

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TY - JOUR

T1 - Pd(OAc)2/CuI-Catalyzed Tandem Reaction for Synthesis of Polysubstituted 3-Chalcogenylindoles

AU - Liu, Ruiting

AU - Li, Zhen

AU - Wang, Shengke

AU - Zhou, Xigeng

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Tandem Pd(OAc)2/CuI catalyzed coupling/cyclization/chalcogenylation reaction of gem-dibromovinylanilines with boronic acids and dichalcogenides has been developed, which provides a new synthetic approach to 3-sulfenyl- and 3-selenylindoles. Various functional groups such as methoxyl, halides and trifluoromethyl groups in the substrates are tolerated.

AB - Tandem Pd(OAc)2/CuI catalyzed coupling/cyclization/chalcogenylation reaction of gem-dibromovinylanilines with boronic acids and dichalcogenides has been developed, which provides a new synthetic approach to 3-sulfenyl- and 3-selenylindoles. Various functional groups such as methoxyl, halides and trifluoromethyl groups in the substrates are tolerated.

KW - Catalysis

KW - Indole

KW - Pd(OAc)/CuI

KW - Synthesis

UR - https://www.scopus.com/pages/publications/85077921475

U2 - 10.6023/cjoc201904032

DO - 10.6023/cjoc201904032

M3 - 文章

AN - SCOPUS:85077921475

SN - 0253-2786

VL - 39

SP - 3215

EP - 3222

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 11

ER -

Pd(OAc)₂/CuI-Catalyzed Tandem Reaction for Synthesis of Polysubstituted 3-Chalcogenylindoles

Abstract

Keywords

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