One-pot synthesis of glycidyl nitrate

Shao Jun Qiu; Xiao Xian Gan; Hui Qing Fan

One-pot synthesis of glycidyl nitrate

Shao Jun Qiu
, Xiao Xian Gan
, Hui Qing Fan

School of Materials Sience and Engineering

Northwestern Polytechnical University Xian
Xi'an Modern Chemistry Research Institute

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt%) resulted in ring-opening reaction at about 20°C. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.

Original language	English
Pages (from-to)	211-213
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	13
Issue number	4
State	Published - Aug 2005

Keywords

Energetic material
Glycidyl nitrate
One-pot synthesis
Organic chemistry
Synthesis

Cite this

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title = "One-pot synthesis of glycidyl nitrate",

abstract = "A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt\%) resulted in ring-opening reaction at about 20°C. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60\%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.",

keywords = "Energetic material, Glycidyl nitrate, One-pot synthesis, Organic chemistry, Synthesis",

author = "Qiu, \{Shao Jun\} and Gan, \{Xiao Xian\} and Fan, \{Hui Qing\}",

year = "2005",

month = aug,

language = "英语",

volume = "13",

pages = "211--213",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "4",

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TY - JOUR

T1 - One-pot synthesis of glycidyl nitrate

AU - Qiu, Shao Jun

AU - Gan, Xiao Xian

AU - Fan, Hui Qing

PY - 2005/8

Y1 - 2005/8

N2 - A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt%) resulted in ring-opening reaction at about 20°C. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.

AB - A mild, low cost synthetic method of glycidyl nitrate is developed via so called one-pot procedure. Epichlorohydrin added dropwise to the dilute nitric acid (35 wt%) resulted in ring-opening reaction at about 20°C. Ring-closing occurred then by the addition of aqueous sodium hydroxide. Glycidyl nitrate was obtained in moderate yield (60%) and its structure was characterized by Fourier transform infrared spectroscopy, hydrogen and carbon nuclear magnetic resonance and elemental analysis.

KW - Energetic material

KW - Glycidyl nitrate

KW - One-pot synthesis

KW - Organic chemistry

KW - Synthesis

UR - https://www.scopus.com/pages/publications/25144518183

M3 - 文章

AN - SCOPUS:25144518183

SN - 1006-9941

VL - 13

SP - 211

EP - 213

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 4

ER -

One-pot synthesis of glycidyl nitrate

Abstract

Keywords

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