One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

Jianan Zhu; Ying Wei; Dongqing Lin; Changjin Ou; Linghai Xie; Yu Zhao; Wei Huang

doi:10.1039/c5ob01781e

One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

Jianan Zhu
, Ying Wei
, Dongqing Lin
, Changjin Ou
, Linghai Xie
, Yu Zhao
, Wei Huang

Nanjing University of Posts and Telecommunications
Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B₂pin₂) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.

Original language	English
Pages (from-to)	11362-11368
Number of pages	7
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	46
DOIs	https://doi.org/10.1039/c5ob01781e
State	Published - 24 Sep 2015
Externally published	Yes

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title = "One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols",

abstract = "Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.",

author = "Jianan Zhu and Ying Wei and Dongqing Lin and Changjin Ou and Linghai Xie and Yu Zhao and Wei Huang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

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day = "24",

doi = "10.1039/c5ob01781e",

language = "英语",

volume = "13",

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TY - JOUR

T1 - One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

AU - Zhu, Jianan

AU - Wei, Ying

AU - Lin, Dongqing

AU - Ou, Changjin

AU - Xie, Linghai

AU - Zhao, Yu

AU - Huang, Wei

PY - 2015/9/24

Y1 - 2015/9/24

N2 - Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.

AB - Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.

UR - https://www.scopus.com/pages/publications/84947803698

U2 - 10.1039/c5ob01781e

DO - 10.1039/c5ob01781e

M3 - 文章

AN - SCOPUS:84947803698

SN - 1477-0520

VL - 13

SP - 11362

EP - 11368

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 46

ER -

One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols

Abstract

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