Novel H-shaped persistent architecture based on a dispiro building block system

Ling Hai Xie; Xiao Ya Hou; Chao Tang; Yu Ran Hua; Rui Jie Wang; Run Feng Chen; Qu Li Fan; Lian Hui Wang; Wei Wei; Bo Peng; Wei Huang

doi:10.1021/ol060109x

Novel H-shaped persistent architecture based on a dispiro building block system

Ling Hai Xie
, Xiao Ya Hou
, Chao Tang
, Yu Ran Hua
, Rui Jie Wang
, Run Feng Chen
, Qu Li Fan
, Lian Hui Wang
, Wei Wei
, Bo Peng
, Wei Huang

Fudan University
Nanjing University
National University of Singapore

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

A novel dispiro building block, dispiro[fluorene-9,5′(7′ H)-diindeno[2,1-b:1′,2′-d]thiophene-7′,9″-fluorene], and its two derivatives, TBP-DSFDITF and TDOF-DSFDITF, were designed and synthesized. Because of the rigidity and orthogonality of the spiro structure, TBP-DSFDITF exhibits a well-defined H-shaped architecture, which consists of two ter(biphenyls) as the arms of the H-shape and 3,4-diphenylthiophene as the rung, connecting via completely rigid dispiro linkages with two sp³ carbon atoms.

Original language	English
Pages (from-to)	1363-1366
Number of pages	4
Journal	Organic Letters
Volume	8
Issue number	7
DOIs	https://doi.org/10.1021/ol060109x
State	Published - 30 Mar 2006
Externally published	Yes

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10.1021/ol060109x

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title = "Novel H-shaped persistent architecture based on a dispiro building block system",

abstract = "A novel dispiro building block, dispiro[fluorene-9,5′(7′ H)-diindeno[2,1-b:1′,2′-d]thiophene-7′,9″-fluorene], and its two derivatives, TBP-DSFDITF and TDOF-DSFDITF, were designed and synthesized. Because of the rigidity and orthogonality of the spiro structure, TBP-DSFDITF exhibits a well-defined H-shaped architecture, which consists of two ter(biphenyls) as the arms of the H-shape and 3,4-diphenylthiophene as the rung, connecting via completely rigid dispiro linkages with two sp3 carbon atoms.",

author = "Xie, \{Ling Hai\} and Hou, \{Xiao Ya\} and Chao Tang and Hua, \{Yu Ran\} and Wang, \{Rui Jie\} and Chen, \{Run Feng\} and Fan, \{Qu Li\} and Wang, \{Lian Hui\} and Wei Wei and Bo Peng and Wei Huang",

year = "2006",

month = mar,

day = "30",

doi = "10.1021/ol060109x",

language = "英语",

volume = "8",

pages = "1363--1366",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Novel H-shaped persistent architecture based on a dispiro building block system

AU - Xie, Ling Hai

AU - Hou, Xiao Ya

AU - Tang, Chao

AU - Hua, Yu Ran

AU - Wang, Rui Jie

AU - Chen, Run Feng

AU - Fan, Qu Li

AU - Wang, Lian Hui

AU - Wei, Wei

AU - Peng, Bo

AU - Huang, Wei

PY - 2006/3/30

Y1 - 2006/3/30

N2 - A novel dispiro building block, dispiro[fluorene-9,5′(7′ H)-diindeno[2,1-b:1′,2′-d]thiophene-7′,9″-fluorene], and its two derivatives, TBP-DSFDITF and TDOF-DSFDITF, were designed and synthesized. Because of the rigidity and orthogonality of the spiro structure, TBP-DSFDITF exhibits a well-defined H-shaped architecture, which consists of two ter(biphenyls) as the arms of the H-shape and 3,4-diphenylthiophene as the rung, connecting via completely rigid dispiro linkages with two sp3 carbon atoms.

AB - A novel dispiro building block, dispiro[fluorene-9,5′(7′ H)-diindeno[2,1-b:1′,2′-d]thiophene-7′,9″-fluorene], and its two derivatives, TBP-DSFDITF and TDOF-DSFDITF, were designed and synthesized. Because of the rigidity and orthogonality of the spiro structure, TBP-DSFDITF exhibits a well-defined H-shaped architecture, which consists of two ter(biphenyls) as the arms of the H-shape and 3,4-diphenylthiophene as the rung, connecting via completely rigid dispiro linkages with two sp3 carbon atoms.

UR - https://www.scopus.com/pages/publications/33645951089

U2 - 10.1021/ol060109x

DO - 10.1021/ol060109x

M3 - 文章

AN - SCOPUS:33645951089

SN - 1523-7060

VL - 8

SP - 1363

EP - 1366

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Novel H-shaped persistent architecture based on a dispiro building block system

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