New Zn(II)/M(I) (M = Na, K and Rb) metal-organic frameworks based on 5-methylisophthalic acid ligand: Syntheses, structures and fluorescent property

Li Ping Xue; Yue Cheng Liu; Yun Hu Han; Chong Bin Tian; Qi Peng Li; Ping Lin; Shao Wu Du

New Zn(II)/M(I) (M = Na, K and Rb) metal-organic frameworks based on 5-methylisophthalic acid ligand: Syntheses, structures and fluorescent property

Li Ping Xue
, Yue Cheng Liu
, Yun Hu Han
, Chong Bin Tian
, Qi Peng Li
, Ping Lin
, Shao Wu Du

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Reactions of Zn(NO₃)₂6H₂O and MNO ₃ (M = Na, K and Rb) with H₂mip (H2mip = 5-methylisophthalic acid) in DMF (DMF = N,N'-dimethylformamide) resulted in the formation of novel heterometallic metal-organic frameworks (Me ₂NH₂)[ZnM(mip)2] (1: M = Na; 2: M = K; 3: M = Rb, mip = 5-methylisophthalate dianion for 1∼3). These complexes belong to the monoclinic system, space group P2/c and have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveal that 1∼3 are 3D isomorphic structures based on a trinuclear unit {ZnM2( μ₂-COO) ₂ ( μ₃-COO)₂} and exhibit pcu topological net and blue fluorescence.

Original language	English
Pages (from-to)	1191-1198
Number of pages	8
Journal	Jiegou Huaxue
Volume	33
Issue number	8
State	Published - 15 Aug 2014
Externally published	Yes

Keywords

Heterometallic
Photoluminescence
Solvothermal synthesis

Cite this

@article{044a0f248ca84f15ab0862d177b60aa7,

title = "New Zn(II)/M(I) (M = Na, K and Rb) metal-organic frameworks based on 5-methylisophthalic acid ligand: Syntheses, structures and fluorescent property",

abstract = "Reactions of Zn(NO3)26H2O and MNO 3 (M = Na, K and Rb) with H2mip (H2mip = 5-methylisophthalic acid) in DMF (DMF = N,N'-dimethylformamide) resulted in the formation of novel heterometallic metal-organic frameworks (Me 2NH2)[ZnM(mip)2] (1: M = Na; 2: M = K; 3: M = Rb, mip = 5-methylisophthalate dianion for 1∼3). These complexes belong to the monoclinic system, space group P2/c and have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveal that 1∼3 are 3D isomorphic structures based on a trinuclear unit \{ZnM2( μ2-COO) 2 ( μ3-COO)2\} and exhibit pcu topological net and blue fluorescence.",

keywords = "Heterometallic, Photoluminescence, Solvothermal synthesis",

author = "Xue, \{Li Ping\} and Liu, \{Yue Cheng\} and Han, \{Yun Hu\} and Tian, \{Chong Bin\} and Li, \{Qi Peng\} and Ping Lin and Du, \{Shao Wu\}",

year = "2014",

month = aug,

day = "15",

language = "英语",

volume = "33",

pages = "1191--1198",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "8",

}

TY - JOUR

T1 - New Zn(II)/M(I) (M = Na, K and Rb) metal-organic frameworks based on 5-methylisophthalic acid ligand

T2 - Syntheses, structures and fluorescent property

AU - Xue, Li Ping

AU - Liu, Yue Cheng

AU - Han, Yun Hu

AU - Tian, Chong Bin

AU - Li, Qi Peng

AU - Lin, Ping

AU - Du, Shao Wu

PY - 2014/8/15

Y1 - 2014/8/15

N2 - Reactions of Zn(NO3)26H2O and MNO 3 (M = Na, K and Rb) with H2mip (H2mip = 5-methylisophthalic acid) in DMF (DMF = N,N'-dimethylformamide) resulted in the formation of novel heterometallic metal-organic frameworks (Me 2NH2)[ZnM(mip)2] (1: M = Na; 2: M = K; 3: M = Rb, mip = 5-methylisophthalate dianion for 1∼3). These complexes belong to the monoclinic system, space group P2/c and have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveal that 1∼3 are 3D isomorphic structures based on a trinuclear unit {ZnM2( μ2-COO) 2 ( μ3-COO)2} and exhibit pcu topological net and blue fluorescence.

AB - Reactions of Zn(NO3)26H2O and MNO 3 (M = Na, K and Rb) with H2mip (H2mip = 5-methylisophthalic acid) in DMF (DMF = N,N'-dimethylformamide) resulted in the formation of novel heterometallic metal-organic frameworks (Me 2NH2)[ZnM(mip)2] (1: M = Na; 2: M = K; 3: M = Rb, mip = 5-methylisophthalate dianion for 1∼3). These complexes belong to the monoclinic system, space group P2/c and have been fully characterized by satisfactory elemental analysis, FT-IR spectra, TGA and single-crystal X-ray diffraction. Single-crystal X-ray diffraction studies reveal that 1∼3 are 3D isomorphic structures based on a trinuclear unit {ZnM2( μ2-COO) 2 ( μ3-COO)2} and exhibit pcu topological net and blue fluorescence.

KW - Heterometallic

KW - Photoluminescence

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/84906303134

M3 - 文章

AN - SCOPUS:84906303134

SN - 0254-5861

VL - 33

SP - 1191

EP - 1198

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 8

ER -

New Zn(II)/M(I) (M = Na, K and Rb) metal-organic frameworks based on 5-methylisophthalic acid ligand: Syntheses, structures and fluorescent property

Abstract

Keywords

Other files and links

Fingerprint

Cite this