MIL-53(Fe) derived MCC/rGO nanoparticles with excellent broadband microwave absorption properties

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Abstract

High efficient MIL-53(Fe) derived γ-Fe2O3 coated by carbon framework (MCC for short) and compound with reduced graphene oxide for broadband microwave absorption is prepared by facile hydrothermal method and gradient temperature calcination. The sheets/bowknot-shaped nanoparticles structure have better microwave absorption performance via uniting magnetic γ-Fe2O3 core, carbon skeleton and rGO sheets. Binary material calcined at 600°C has an optimal RL value −62.53dB under 2.66mm thickness. In addition, the ternary MCC/rGO of 700°C calcination has better performance with an 11.68GHz effective absorption bandwidth (from 6.32GHz to 18GHz) of a single thickness of 3.60mm, and a maximum RL of −43.13dB at 3.25mm thickness. The MOF framework enhances particle stability and internal scattering, while graphene provides a larger absorption surface, coupled with the good impedance matching rooted in suitable permittivity and permeability, the material is an ideal new type of absorbing material.

Original languageEnglish
Article number100362
JournalComposites Communications
Volume21
DOIs
StatePublished - Oct 2020

Keywords

  • Broadband absorption
  • Metal-organic framework
  • Microwave absorption
  • Reduced graphene oxide

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