Microstructure evolution and hot corrosion behavior of Zr-Y modified silicide coating prepared by two-step process

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Abstract

Zr-Y modified silicide coating on the Nb-Si based ultrahigh temperature alloy is prepared by firstly magnetron sputtering Ti-5Al-10Nb-2Zr (at.%) alloy film and then Si-Y co-deposition. The coating is mainly composed of a TiSi2 outer layer, a relatively thick (Nb,X) Si2 inner layer and a thin transitional layer. The mass gain of the bare alloy, simple Si-Y coating and two-step coating is 97, 7.3 and 4.1 mg/cm2 respectively after hot corrosion at 900 °C for 100 h in Na2SO4+NaCl molten salts. The hot corrosion mechanism of the coating has been revealed.

Original languageEnglish
Pages (from-to)44-57
Number of pages14
JournalCorrosion Science
Volume156
DOIs
StatePublished - 1 Aug 2019

Keywords

  • A. Metal coatings
  • A. Molten salts
  • B. EPMA
  • C. Hot corrosion

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