Microscale synthesis of multiblock copolymers using ultrafast RAFT polymerisation

Joji Tanaka; Pratik Gurnani; Alexander B. Cook; Satu Häkkinen; Junliang Zhang; Jie Yang; Andrew Kerr; David M. Haddleton; Sébastien Perrier; Paul Wilson

doi:10.1039/c8py01437j

Microscale synthesis of multiblock copolymers using ultrafast RAFT polymerisation

Joji Tanaka
, Pratik Gurnani
, Alexander B. Cook
, Satu Häkkinen
, Junliang Zhang
, Jie Yang
, Andrew Kerr
, David M. Haddleton
, Sébastien Perrier
, Paul Wilson

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

We demonstrate that ultrafast RAFT in the presence of air can be scaled down to 2 μL with good control using microvolume insert vials as the polymerisation vessel. By careful cooling and mixing of the sequential monomers, well-defined pentablock copolymers were generated with a final volume of 10 μL.

Original language	English
Pages (from-to)	1186-1191
Number of pages	6
Journal	Polymer Chemistry
Volume	10
Issue number	10
DOIs	https://doi.org/10.1039/c8py01437j
State	Published - 14 Mar 2019
Externally published	Yes

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10.1039/c8py01437j

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title = "Microscale synthesis of multiblock copolymers using ultrafast RAFT polymerisation",

abstract = "We demonstrate that ultrafast RAFT in the presence of air can be scaled down to 2 μL with good control using microvolume insert vials as the polymerisation vessel. By careful cooling and mixing of the sequential monomers, well-defined pentablock copolymers were generated with a final volume of 10 μL.",

author = "Joji Tanaka and Pratik Gurnani and Cook, \{Alexander B.\} and Satu H{\"a}kkinen and Junliang Zhang and Jie Yang and Andrew Kerr and Haddleton, \{David M.\} and S{\'e}bastien Perrier and Paul Wilson",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

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day = "14",

doi = "10.1039/c8py01437j",

language = "英语",

volume = "10",

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journal = "Polymer Chemistry",

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T1 - Microscale synthesis of multiblock copolymers using ultrafast RAFT polymerisation

AU - Tanaka, Joji

AU - Gurnani, Pratik

AU - Cook, Alexander B.

AU - Häkkinen, Satu

AU - Zhang, Junliang

AU - Yang, Jie

AU - Kerr, Andrew

AU - Haddleton, David M.

AU - Perrier, Sébastien

AU - Wilson, Paul

PY - 2019/3/14

Y1 - 2019/3/14

N2 - We demonstrate that ultrafast RAFT in the presence of air can be scaled down to 2 μL with good control using microvolume insert vials as the polymerisation vessel. By careful cooling and mixing of the sequential monomers, well-defined pentablock copolymers were generated with a final volume of 10 μL.

AB - We demonstrate that ultrafast RAFT in the presence of air can be scaled down to 2 μL with good control using microvolume insert vials as the polymerisation vessel. By careful cooling and mixing of the sequential monomers, well-defined pentablock copolymers were generated with a final volume of 10 μL.

UR - https://www.scopus.com/pages/publications/85062655606

U2 - 10.1039/c8py01437j

DO - 10.1039/c8py01437j

M3 - 文章

AN - SCOPUS:85062655606

SN - 1759-9954

VL - 10

SP - 1186

EP - 1191

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 10

ER -

Microscale synthesis of multiblock copolymers using ultrafast RAFT polymerisation

Abstract

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