Abstract
Hot cracking remains a critical challenge limiting the widespread adoption of superalloys in additive manufacturing. This defect primarily originates from stress-induced rupture of intergranular residual liquid films that persist during final solidification, typically comprising low-melting-point phases formed through solute-segregation. This understanding has guided conventional crack suppression strategies focused on eliminating such residual phases by strict compositional controls. Herein, an innovative approach is demonstrated that strategically engineers residual eutectic fractions (≥2 vol.%) through trace element regulation to achieve an intrinsic capability for crack suppression. Hastelloy X is selected as the model system owing to its marked hot cracking susceptibility. Leveraging the ultra-low partition coefficient ( k = 0.21) of carbon, a subtle increment in its content (<0.1 wt.%) significantly enhances the formation of ternary eutectic carbides through amplified segregation. The resulting adequate eutectic liquids successfully prevent crack initiation through stress-compensating backfilling while preserving structural cohesion via liquid buffering, revealing the context-dependent duality of eutectics—transitioning from crack initiators to healers. These crack-free samples exhibit superior strength–ductility synergy compared to carbon-restricted counterparts, benefiting from combined effects of carbide dispersion strengthening and multiple dynamic hardening mechanisms.
| Original language | English |
|---|---|
| Article number | 121668 |
| Journal | Acta Materialia |
| Volume | 302 |
| DOIs | |
| State | Published - 1 Jan 2026 |
Keywords
- Additive manufacturing
- Hot cracking
- Segregation engineering
- Solidification
- Superalloy
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