Abstract
Monodisperse macrospirocyclic oligomers were prepared using self-condensation of the Friedel-Crafts reaction. Through the C-9s of the central fluorene units of four surrounding oligofluorenes, four carbazole units are connected in a series to form a macrocyclic core. These rodlike oligofluorenes form a rigid three-dimensional structure, affording the resulting macrocyclics a high steric hindrance for close interchain packing.
| Original language | English |
|---|---|
| Pages (from-to) | 200-203 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 13 |
| Issue number | 2 |
| DOIs | |
| State | Published - 21 Jan 2011 |
| Externally published | Yes |
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