Inverse CO2/C2H2 separation assisted by coordinated water in a dysprosium(iii) metal-organic framework

Bo Kai Ling; Min Zeng; Tao Zhang; Jian Wei Cao; Rong Yang; Lu Cheng; Chi Yu Zhang; Yu Wang; Kai Jie Chen

doi:10.1039/d3cc03519k

Inverse CO₂/C₂H₂ separation assisted by coordinated water in a dysprosium(iii) metal-organic framework

Bo Kai Ling, Min Zeng, Tao Zhang, Jian Wei Cao, Rong Yang, Lu Cheng, Chi Yu Zhang, Yu Wang, Kai Jie Chen

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

An ultramicroporous metal-organic framework (MOF) constructed from dysprosium(iii) and oxalate, termed Dy-F-oxa, is carefully studied for inverse separation of CO₂ from C₂H₂. Adsorption experiments and modeling studies reveal that the high CO₂ adsorption is attributed to the preferential sites for CO₂ by coordinated water. After the equimolar gas mixture breakthrough experiment, C₂H₂ can be directly produced as a pure effluent.

Original language	English
Pages (from-to)	10952-10955
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	73
DOIs	https://doi.org/10.1039/d3cc03519k
State	Published - 15 Aug 2023

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title = "Inverse CO2/C2H2 separation assisted by coordinated water in a dysprosium(iii) metal-organic framework",

abstract = "An ultramicroporous metal-organic framework (MOF) constructed from dysprosium(iii) and oxalate, termed Dy-F-oxa, is carefully studied for inverse separation of CO2 from C2H2. Adsorption experiments and modeling studies reveal that the high CO2 adsorption is attributed to the preferential sites for CO2 by coordinated water. After the equimolar gas mixture breakthrough experiment, C2H2 can be directly produced as a pure effluent.",

author = "Ling, \{Bo Kai\} and Min Zeng and Tao Zhang and Cao, \{Jian Wei\} and Rong Yang and Lu Cheng and Zhang, \{Chi Yu\} and Yu Wang and Chen, \{Kai Jie\}",

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doi = "10.1039/d3cc03519k",

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T1 - Inverse CO2/C2H2 separation assisted by coordinated water in a dysprosium(iii) metal-organic framework

AU - Ling, Bo Kai

AU - Zeng, Min

AU - Zhang, Tao

AU - Cao, Jian Wei

AU - Yang, Rong

AU - Cheng, Lu

AU - Zhang, Chi Yu

AU - Wang, Yu

AU - Chen, Kai Jie

PY - 2023/8/15

Y1 - 2023/8/15

N2 - An ultramicroporous metal-organic framework (MOF) constructed from dysprosium(iii) and oxalate, termed Dy-F-oxa, is carefully studied for inverse separation of CO2 from C2H2. Adsorption experiments and modeling studies reveal that the high CO2 adsorption is attributed to the preferential sites for CO2 by coordinated water. After the equimolar gas mixture breakthrough experiment, C2H2 can be directly produced as a pure effluent.

AB - An ultramicroporous metal-organic framework (MOF) constructed from dysprosium(iii) and oxalate, termed Dy-F-oxa, is carefully studied for inverse separation of CO2 from C2H2. Adsorption experiments and modeling studies reveal that the high CO2 adsorption is attributed to the preferential sites for CO2 by coordinated water. After the equimolar gas mixture breakthrough experiment, C2H2 can be directly produced as a pure effluent.

UR - https://www.scopus.com/pages/publications/85169511163

U2 - 10.1039/d3cc03519k

DO - 10.1039/d3cc03519k

M3 - 文章

C2 - 37606637

AN - SCOPUS:85169511163

SN - 1359-7345

VL - 59

SP - 10952

EP - 10955

JO - Chemical Communications

JF - Chemical Communications

IS - 73

ER -

Inverse CO₂/C₂H₂ separation assisted by coordinated water in a dysprosium(iii) metal-organic framework

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