Interior and Surface Synergistic Modifications Modulate the SnNb2O6/Ni-Doped ZnIn2S4S-Scheme Heterojunction for Efficient Photocatalytic H2Evolution

Chunxue Li; Xiaoteng Liu; Guixiang Ding; Pengwei Huo; Yan Yan; Yongsheng Yan; Guangfu Liao

doi:10.1021/acs.inorgchem.1c03936

Interior and Surface Synergistic Modifications Modulate the SnNb₂O₆/Ni-Doped ZnIn₂S₄S-Scheme Heterojunction for Efficient Photocatalytic H₂Evolution

Chunxue Li
, Xiaoteng Liu
, Guixiang Ding
, Pengwei Huo
, Yan Yan
, Yongsheng Yan
, Guangfu Liao

Jiangsu University
Liaoning Normal University
China University of Geosciences, Wuhan

Research output: Contribution to journal › Article › peer-review

65 Scopus citations

Abstract

Interior and surface synergistic modifications can endow the photocatalytic reaction with tuned photogenerated carrier flow at the atomic level. Herein, a new class of 2D/2D SnNb₂O₆/Ni-doped ZnIn₂S₄(SNO/Ni-ZIS) S-scheme heterojunctions is synthesized by a simple hydrothermal strategy, which was used to evaluate the synergy between interior and surface modifications. Theoretical calculations show that the S-scheme heterojunction boosts the desorption of H atoms for rapid H₂evolution. As a result, 25% SNO/Ni_0.4-ZIS exhibits significantly improved PHE activity under visible light, roughly 4.49 and 2.00 times stronger than that of single ZIS and Ni_0.4-ZIS, respectively. In addition, 25% SNO/Ni_0.4-ZIS also shows superior structural stability. This work provides advanced insight for developing high-performance S-scheme systems from photocatalyst design to mechanistic insight.

Original language	English
Pages (from-to)	4681-4689
Number of pages	9
Journal	Inorganic Chemistry
Volume	61
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.1c03936
State	Published - 21 Mar 2022
Externally published	Yes

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10.1021/acs.inorgchem.1c03936

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title = "Interior and Surface Synergistic Modifications Modulate the SnNb2O6/Ni-Doped ZnIn2S4S-Scheme Heterojunction for Efficient Photocatalytic H2Evolution",

abstract = "Interior and surface synergistic modifications can endow the photocatalytic reaction with tuned photogenerated carrier flow at the atomic level. Herein, a new class of 2D/2D SnNb2O6/Ni-doped ZnIn2S4(SNO/Ni-ZIS) S-scheme heterojunctions is synthesized by a simple hydrothermal strategy, which was used to evaluate the synergy between interior and surface modifications. Theoretical calculations show that the S-scheme heterojunction boosts the desorption of H atoms for rapid H2evolution. As a result, 25\% SNO/Ni0.4-ZIS exhibits significantly improved PHE activity under visible light, roughly 4.49 and 2.00 times stronger than that of single ZIS and Ni0.4-ZIS, respectively. In addition, 25\% SNO/Ni0.4-ZIS also shows superior structural stability. This work provides advanced insight for developing high-performance S-scheme systems from photocatalyst design to mechanistic insight.",

author = "Chunxue Li and Xiaoteng Liu and Guixiang Ding and Pengwei Huo and Yan Yan and Yongsheng Yan and Guangfu Liao",

year = "2022",

month = mar,

day = "21",

doi = "10.1021/acs.inorgchem.1c03936",

language = "英语",

volume = "61",

pages = "4681--4689",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Interior and Surface Synergistic Modifications Modulate the SnNb2O6/Ni-Doped ZnIn2S4S-Scheme Heterojunction for Efficient Photocatalytic H2Evolution

AU - Li, Chunxue

AU - Liu, Xiaoteng

AU - Ding, Guixiang

AU - Huo, Pengwei

AU - Yan, Yan

AU - Yan, Yongsheng

AU - Liao, Guangfu

PY - 2022/3/21

Y1 - 2022/3/21

N2 - Interior and surface synergistic modifications can endow the photocatalytic reaction with tuned photogenerated carrier flow at the atomic level. Herein, a new class of 2D/2D SnNb2O6/Ni-doped ZnIn2S4(SNO/Ni-ZIS) S-scheme heterojunctions is synthesized by a simple hydrothermal strategy, which was used to evaluate the synergy between interior and surface modifications. Theoretical calculations show that the S-scheme heterojunction boosts the desorption of H atoms for rapid H2evolution. As a result, 25% SNO/Ni0.4-ZIS exhibits significantly improved PHE activity under visible light, roughly 4.49 and 2.00 times stronger than that of single ZIS and Ni0.4-ZIS, respectively. In addition, 25% SNO/Ni0.4-ZIS also shows superior structural stability. This work provides advanced insight for developing high-performance S-scheme systems from photocatalyst design to mechanistic insight.

AB - Interior and surface synergistic modifications can endow the photocatalytic reaction with tuned photogenerated carrier flow at the atomic level. Herein, a new class of 2D/2D SnNb2O6/Ni-doped ZnIn2S4(SNO/Ni-ZIS) S-scheme heterojunctions is synthesized by a simple hydrothermal strategy, which was used to evaluate the synergy between interior and surface modifications. Theoretical calculations show that the S-scheme heterojunction boosts the desorption of H atoms for rapid H2evolution. As a result, 25% SNO/Ni0.4-ZIS exhibits significantly improved PHE activity under visible light, roughly 4.49 and 2.00 times stronger than that of single ZIS and Ni0.4-ZIS, respectively. In addition, 25% SNO/Ni0.4-ZIS also shows superior structural stability. This work provides advanced insight for developing high-performance S-scheme systems from photocatalyst design to mechanistic insight.

UR - https://www.scopus.com/pages/publications/85126557228

U2 - 10.1021/acs.inorgchem.1c03936

DO - 10.1021/acs.inorgchem.1c03936

M3 - 文章

C2 - 35258950

AN - SCOPUS:85126557228

SN - 0020-1669

VL - 61

SP - 4681

EP - 4689

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Interior and Surface Synergistic Modifications Modulate the SnNb₂O₆/Ni-Doped ZnIn₂S₄S-Scheme Heterojunction for Efficient Photocatalytic H₂Evolution

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