Interfacial engineering of vacancy-rich nitrogen-doped Fe_xO_y@MoS₂ Co-catalytic carbonaceous beads mediated non-radicals for fast catalytic oxidation

How to accelerate the Fe³⁺/Fe²⁺ conversion and fabricate recyclable iron-based catalysts with high reactivity and stability is highly desired yet challenging. Herein, vacancy-rich N@Fe_xO_y@MoS₂ carbonaceous beads were firstly developed via employing sodium alginate, molybdenum disulfide (MoS₂), and Fe-ZIFs through sol-gel self-assembly, followed by in-situ growth and pyrolysis strategies. As expected, A series of characterizations reflected that N@Fe_xO_y@MoS₂ had high dispersibility and conductivity for fast mass and electron transport, and MoS₂ as co-catalyst accelerated the circulation of Fe³⁺ to Fe²⁺ that attained 99.4% (0.345 min⁻¹) norfloxacin degradation via PMS activation in a synergistic ‘‘adsorption-driven-oxidation’’ process, which much outperformed those of pure MoS₂ (32.4%) and N@Fe_xO_y powder catalyst (45.3%). Moreover, confined Fe species, graphitic N, pyrrolic N, pyridinic N, and sulfur/oxygen vacancies were found as highly exposed active sites that contributed to the activation of PMS to dominate non-radicals (¹O₂ and O₂·^-) and other radicals following a contribution order ¹O₂ > O₂·^- > SO₄·^- > ^·OH. More importantly^, a fluidized-bed catalytic unit was evaluated and maintained the continuous zero discharge of NX. Overall, this study offered a generally applicable approach to fabricate removable Fe-based catalysts for contaminants remediation.