In situ surface assembly of core-shell TiO2-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

Wei Ji; Jian Qu; Cheng An Li; Jing Wei Wu; Su Jing; Fei Gao; Yi Nong Lv; Chang Liu; Dun Ru Zhu; Xiao Min Ren; Wei Huang

doi:10.1016/j.apcatb.2016.12.041

In situ surface assembly of core-shell TiO₂-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

Wei Ji
, Jian Qu
, Cheng An Li
, Jing Wei Wu
, Su Jing
, Fei Gao
, Yi Nong Lv
, Chang Liu
, Dun Ru Zhu
, Xiao Min Ren
, Wei Huang

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

1D loop chain copper(I) cluster, [Cu₂I₂L₂]_n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu₂I₂L₂]_non the surface of TiO₂nanoparticles. The visible-light photocatalytic property of core-shell TiO₂-[Cu₂I₂L₂]_nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.

Original language	English
Pages (from-to)	368-375
Number of pages	8
Journal	Applied Catalysis B: Environmental
Volume	205
DOIs	https://doi.org/10.1016/j.apcatb.2016.12.041
State	Published - 2017
Externally published	Yes

Keywords

Charge-transfer complex
Polymeric [CuIL]cluster
Selenoanthracene
TiO
Visible-light photocatalyst

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10.1016/j.apcatb.2016.12.041

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@article{31adb1ffaa104376976f1b9615182074,

title = "In situ surface assembly of core-shell TiO2-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)",

abstract = "1D loop chain copper(I) cluster, [Cu2I2L2]n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu2I2L2]non the surface of TiO2nanoparticles. The visible-light photocatalytic property of core-shell TiO2-[Cu2I2L2]nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.",

keywords = "Charge-transfer complex, Polymeric [CuIL]cluster, Selenoanthracene, TiO, Visible-light photocatalyst",

author = "Wei Ji and Jian Qu and Li, \{Cheng An\} and Wu, \{Jing Wei\} and Su Jing and Fei Gao and Lv, \{Yi Nong\} and Chang Liu and Zhu, \{Dun Ru\} and Ren, \{Xiao Min\} and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

doi = "10.1016/j.apcatb.2016.12.041",

language = "英语",

volume = "205",

pages = "368--375",

journal = "Applied Catalysis B: Environmental",

issn = "0926-3373",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - In situ surface assembly of core-shell TiO2-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

AU - Ji, Wei

AU - Qu, Jian

AU - Li, Cheng An

AU - Wu, Jing Wei

AU - Jing, Su

AU - Gao, Fei

AU - Lv, Yi Nong

AU - Liu, Chang

AU - Zhu, Dun Ru

AU - Ren, Xiao Min

AU - Huang, Wei

PY - 2017

Y1 - 2017

N2 - 1D loop chain copper(I) cluster, [Cu2I2L2]n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu2I2L2]non the surface of TiO2nanoparticles. The visible-light photocatalytic property of core-shell TiO2-[Cu2I2L2]nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.

AB - 1D loop chain copper(I) cluster, [Cu2I2L2]n, can be obtained based upon 9-(3-phenylselanyl-2-phenylselanylmethylpropyl)anthracene (L) and CuI. A facile in situ surface assembly strategy was designed to construct polymeric [Cu2I2L2]non the surface of TiO2nanoparticles. The visible-light photocatalytic property of core-shell TiO2-[Cu2I2L2]nwas confirmed by effective reduction of aqueous chromium(VI), showing a clear correlation to optical absorption (Eg = 2.8 eV). The key points of this strategy include high reactivity between copper(I) and soft selenium atom, efficient charge-transfer through polymeric cluster shell, and visible-light photoactivity of copper(I) halogen clusters.

KW - Charge-transfer complex

KW - Polymeric [CuIL]cluster

KW - Selenoanthracene

KW - TiO

KW - Visible-light photocatalyst

UR - https://www.scopus.com/pages/publications/85008697735

U2 - 10.1016/j.apcatb.2016.12.041

DO - 10.1016/j.apcatb.2016.12.041

M3 - 文章

AN - SCOPUS:85008697735

SN - 0926-3373

VL - 205

SP - 368

EP - 375

JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

ER -

In situ surface assembly of core-shell TiO₂-copper(I) cluster nanocomposites for visible-light photocatalytic reduction of Cr(VI)

Abstract

Keywords

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