In situ observation of remelting induced anomalous eutectic structure formation in an undercooled Ni-18.7 at.% Sn eutectic alloy

The forming mechanism of anomalous eutectic structure (AES) in undercooled eutectic alloys has been a controversial issue. In this work, we conducted in situ observation of the AES forming process in an Ni-18.7 at.% Sn eutectic alloy using a high-temperature laser scanning confocal microscope. Our results provide an evidence of the AES formation induced by remelting of primary eutectic lamellae constituted by Ni₃Sn and α-Ni lamellae. During recalescence, a pronounced remelting of the Ni₃Sn phase into liquid occurs, while the α-Ni lamellae subject to a rapid morphological transition into granules. Eventually, the completion of solidification leads to the AES formation.