Hyperbranched organosilicon polymers

Guobin Zhang; Xiaodong Fan; Jie Kong; Yuyang Liu; Yunchuan Xie

Hyperbranched organosilicon polymers

Guobin Zhang
, Xiaodong Fan
, Jie Kong
, Yuyang Liu
, Yunchuan Xie

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian
Xi'an Jiaotong University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Hyperbranched organosilicon polymers (HBOSP), a new kind of functional semi-organic polymers are of great potential to be applied in catalyst carriers, ceramic precursors, electroluminescent polymers, heat-resistant elastomers, etc. In this paper, new methods in recent 10 years for syntheses of HBOSP from new monomers, including AB_x monomer, A₂-B_x or A₂-B′ B_x-1 monomers pair and B_f-AB _x monomers pair, are summarized. Particularly, the research progress on regulation of macromolecular weight and its distribution as well as degree of branching, are discussed. The emphasis is also put on their terminal functional modifications as well as corresponding applications. Finally, new research trends are reviewed based on the progress of HBOSP.

Original language	English
Pages (from-to)	326-338
Number of pages	13
Journal	Progress in Chemistry
Volume	20
Issue number	2-3
State	Published - Mar 2008

Keywords

Degree of branching
Hyperbranched organosilicon polymers
Molecular weight distribution
Terminal modification

Cite this

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title = "Hyperbranched organosilicon polymers",

abstract = "Hyperbranched organosilicon polymers (HBOSP), a new kind of functional semi-organic polymers are of great potential to be applied in catalyst carriers, ceramic precursors, electroluminescent polymers, heat-resistant elastomers, etc. In this paper, new methods in recent 10 years for syntheses of HBOSP from new monomers, including ABx monomer, A2-Bx or A2-B′ Bx-1 monomers pair and Bf-AB x monomers pair, are summarized. Particularly, the research progress on regulation of macromolecular weight and its distribution as well as degree of branching, are discussed. The emphasis is also put on their terminal functional modifications as well as corresponding applications. Finally, new research trends are reviewed based on the progress of HBOSP.",

keywords = "Degree of branching, Hyperbranched organosilicon polymers, Molecular weight distribution, Terminal modification",

author = "Guobin Zhang and Xiaodong Fan and Jie Kong and Yuyang Liu and Yunchuan Xie",

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journal = "Progress in Chemistry",

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T1 - Hyperbranched organosilicon polymers

AU - Zhang, Guobin

AU - Fan, Xiaodong

AU - Kong, Jie

AU - Liu, Yuyang

AU - Xie, Yunchuan

PY - 2008/3

Y1 - 2008/3

N2 - Hyperbranched organosilicon polymers (HBOSP), a new kind of functional semi-organic polymers are of great potential to be applied in catalyst carriers, ceramic precursors, electroluminescent polymers, heat-resistant elastomers, etc. In this paper, new methods in recent 10 years for syntheses of HBOSP from new monomers, including ABx monomer, A2-Bx or A2-B′ Bx-1 monomers pair and Bf-AB x monomers pair, are summarized. Particularly, the research progress on regulation of macromolecular weight and its distribution as well as degree of branching, are discussed. The emphasis is also put on their terminal functional modifications as well as corresponding applications. Finally, new research trends are reviewed based on the progress of HBOSP.

AB - Hyperbranched organosilicon polymers (HBOSP), a new kind of functional semi-organic polymers are of great potential to be applied in catalyst carriers, ceramic precursors, electroluminescent polymers, heat-resistant elastomers, etc. In this paper, new methods in recent 10 years for syntheses of HBOSP from new monomers, including ABx monomer, A2-Bx or A2-B′ Bx-1 monomers pair and Bf-AB x monomers pair, are summarized. Particularly, the research progress on regulation of macromolecular weight and its distribution as well as degree of branching, are discussed. The emphasis is also put on their terminal functional modifications as well as corresponding applications. Finally, new research trends are reviewed based on the progress of HBOSP.

KW - Degree of branching

KW - Hyperbranched organosilicon polymers

KW - Molecular weight distribution

KW - Terminal modification

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M3 - 文章

AN - SCOPUS:42349110290

SN - 1005-281X

VL - 20

SP - 326

EP - 338

JO - Progress in Chemistry

JF - Progress in Chemistry

IS - 2-3

ER -

Hyperbranched organosilicon polymers

Abstract

Keywords

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