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Hybrid ultramicroporous materials (HUMs) with enhanced stability and trace carbon capture performance

  • Amrit Kumar
  • , Carol Hua
  • , David G. Madden
  • , Daniel O'Nolan
  • , Kai Jie Chen
  • , Lee Ann J. Keane
  • , John J. Perry
  • , Michael J. Zaworotko

Research output: Contribution to journalArticlepeer-review

118 Scopus citations

Abstract

Fine-tuning of HUMs through pillar substitution can significantly enhance trace CO2 sorption performance and stability. The resulting materials, exemplified by the new material TIFSIX-3-Ni, [Ni(pyrazine)2(TiF6)]n, are shown through temperature programmed desorption experiments to remove trace quantities of CO2 from moist gas mixtures.

Original languageEnglish
Pages (from-to)5946-5949
Number of pages4
JournalChemical Communications
Volume53
Issue number44
DOIs
StatePublished - 2017
Externally publishedYes

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