Hybrid nanoarrays of Cu-MOFs@H-substituted graphdiyne with various levels of Lewis acidity for nitrate electroreduction

Jiahao Ma; Ru Wang; Biwen Wang; Jiaxin Luo; Qiuyu Zhang; Sifei Zhuo

doi:10.1039/d2cc06989j

Hybrid nanoarrays of Cu-MOFs@H-substituted graphdiyne with various levels of Lewis acidity for nitrate electroreduction

Jiahao Ma
, Ru Wang
, Biwen Wang
, Jiaxin Luo
, Qiuyu Zhang
, Sifei Zhuo

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu²⁺ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.

Original language	English
Pages (from-to)	4348-4351
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	29
DOIs	https://doi.org/10.1039/d2cc06989j
State	Published - 13 Mar 2023

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abstract = "To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu2+ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.",

author = "Jiahao Ma and Ru Wang and Biwen Wang and Jiaxin Luo and Qiuyu Zhang and Sifei Zhuo",

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AU - Ma, Jiahao

AU - Wang, Ru

AU - Wang, Biwen

AU - Luo, Jiaxin

AU - Zhang, Qiuyu

AU - Zhuo, Sifei

PY - 2023/3/13

Y1 - 2023/3/13

N2 - To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu2+ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.

AB - To mimic enzymes in nature, a set of hybrid nanoarrays of Cu-MOFs sealed in hydrogen-substituted graphdiyne has been developed in order to serve as Lewis-acid-promoted catalysts. By regulating the electron-withdrawing capability of the ligands bridging Cu2+ sites, these Cu-MOFs provided different levels of Lewis acidity toward nitrate affinity, a feature crucial for nitrate-to-ammonia conversion.

UR - https://www.scopus.com/pages/publications/85152171404

U2 - 10.1039/d2cc06989j

DO - 10.1039/d2cc06989j

M3 - 文章

C2 - 36946210

AN - SCOPUS:85152171404

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Hybrid nanoarrays of Cu-MOFs@H-substituted graphdiyne with various levels of Lewis acidity for nitrate electroreduction

Abstract

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