Hollow molecularly imprinted fluorescent sensor using europium complex as functional monomer for the detection of trace 2,4,6-trichlorophenol in real water samples

As an important environmental indicator, 2,4,6-trichlorophenol (2,4,6-TCP) was proved extremely harmful to human body. In this article, hollow molecularly imprinted fluorescent polymers (@MIPs) for the selective detection of 2,4,6-TCP were devised and fabricated by sacrificial skeleton method based on SiO₂ nanoparticles. As the most innovation, highly luminescent europium complex Eu(MAA)₃phen played the role of both fluorophores and functional monomers of the MIPs. The obtained @MIPs showed monodispersity and the average particle size was around 130 nm. It had a linear fluorescent response within the concentration range 10–100 nmol L⁻¹ with the correlation coefficient calculated as 0.99625, and the limit of detection was identified as 2.41 nmol L⁻¹. The results show that Eu(MAA)₃phen as a fluorophore has high luminescent properties, and as a functional monomer, it can improve the selectivity and anti-interference performance of MIPs. Furthermore, the hollow structure made it possible that the imprinted specific recognition sites distributed on both inner and outer surfaces of @MIPs. The experimental results showed that these @MIPs could be employed to the selective detection of chlorophenols under low concentration. And this work will provide a reference for further optimization of fluorescent imprinted sensors.