High-Rate and High-Voltage Aqueous Rechargeable Zinc Ammonium Hybrid Battery from Selective Cation Intercalation Cathode

Chunyang Li; Jianghua Wu; Fuxiang Ma; Yuhui Chen; Lijun Fu; Yusong Zhu; Yi Zhang; Peng Wang; Yuping Wu; Wei Huang

doi:10.1021/acsaem.9b01469

High-Rate and High-Voltage Aqueous Rechargeable Zinc Ammonium Hybrid Battery from Selective Cation Intercalation Cathode

Chunyang Li, Jianghua Wu, Fuxiang Ma, Yuhui Chen, Lijun Fu, Yusong Zhu, Yi Zhang, Peng Wang, Yuping Wu, Wei Huang

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

The shortage of lithium resources is promoting the development of cost-efficient battery candidates, especially aqueous rechargeable batteries (ARBs) with high safety and power density. Copper hexacyanoferrate (CuHCF) nanoparticles with high redox potential and rate capability is employed as the battery cathode for hosting ammonium-ion coupling with low-cost zinc anode. Benefiting from the selective ammonium-ion channel in CuHCF, an aqueous rechargeable zinc ammonium hybrid battery is successfully engineered. It presents high cell voltage (1.8 V), outstanding rate performance, low self-discharge, and satisfactory energy density of 114 Wh kg^-1 in consideration of total electrodes' active mass.

Original language	English
Pages (from-to)	6984-6989
Number of pages	6
Journal	ACS Applied Energy Materials
Volume	2
Issue number	10
DOIs	https://doi.org/10.1021/acsaem.9b01469
State	Published - 28 Oct 2019
Externally published	Yes

Keywords

ammonium-ion insertion
high voltage
hybrid battery
Prussian blue analogue
selective ion channel

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10.1021/acsaem.9b01469

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title = "High-Rate and High-Voltage Aqueous Rechargeable Zinc Ammonium Hybrid Battery from Selective Cation Intercalation Cathode",

abstract = "The shortage of lithium resources is promoting the development of cost-efficient battery candidates, especially aqueous rechargeable batteries (ARBs) with high safety and power density. Copper hexacyanoferrate (CuHCF) nanoparticles with high redox potential and rate capability is employed as the battery cathode for hosting ammonium-ion coupling with low-cost zinc anode. Benefiting from the selective ammonium-ion channel in CuHCF, an aqueous rechargeable zinc ammonium hybrid battery is successfully engineered. It presents high cell voltage (1.8 V), outstanding rate performance, low self-discharge, and satisfactory energy density of 114 Wh kg-1 in consideration of total electrodes' active mass.",

keywords = "ammonium-ion insertion, high voltage, hybrid battery, Prussian blue analogue, selective ion channel",

author = "Chunyang Li and Jianghua Wu and Fuxiang Ma and Yuhui Chen and Lijun Fu and Yusong Zhu and Yi Zhang and Peng Wang and Yuping Wu and Wei Huang",

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T1 - High-Rate and High-Voltage Aqueous Rechargeable Zinc Ammonium Hybrid Battery from Selective Cation Intercalation Cathode

AU - Li, Chunyang

AU - Wu, Jianghua

AU - Ma, Fuxiang

AU - Chen, Yuhui

AU - Fu, Lijun

AU - Zhu, Yusong

AU - Zhang, Yi

AU - Wang, Peng

AU - Wu, Yuping

AU - Huang, Wei

PY - 2019/10/28

Y1 - 2019/10/28

N2 - The shortage of lithium resources is promoting the development of cost-efficient battery candidates, especially aqueous rechargeable batteries (ARBs) with high safety and power density. Copper hexacyanoferrate (CuHCF) nanoparticles with high redox potential and rate capability is employed as the battery cathode for hosting ammonium-ion coupling with low-cost zinc anode. Benefiting from the selective ammonium-ion channel in CuHCF, an aqueous rechargeable zinc ammonium hybrid battery is successfully engineered. It presents high cell voltage (1.8 V), outstanding rate performance, low self-discharge, and satisfactory energy density of 114 Wh kg-1 in consideration of total electrodes' active mass.

AB - The shortage of lithium resources is promoting the development of cost-efficient battery candidates, especially aqueous rechargeable batteries (ARBs) with high safety and power density. Copper hexacyanoferrate (CuHCF) nanoparticles with high redox potential and rate capability is employed as the battery cathode for hosting ammonium-ion coupling with low-cost zinc anode. Benefiting from the selective ammonium-ion channel in CuHCF, an aqueous rechargeable zinc ammonium hybrid battery is successfully engineered. It presents high cell voltage (1.8 V), outstanding rate performance, low self-discharge, and satisfactory energy density of 114 Wh kg-1 in consideration of total electrodes' active mass.

KW - ammonium-ion insertion

KW - high voltage

KW - hybrid battery

KW - Prussian blue analogue

KW - selective ion channel

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ER -

High-Rate and High-Voltage Aqueous Rechargeable Zinc Ammonium Hybrid Battery from Selective Cation Intercalation Cathode

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Keywords

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