TY - JOUR
T1 - Growing crystalline selenidostannates in deep eutectic solvent
AU - Cai, Ting
AU - Zhu, Jian Nan
AU - Cheng, Fang Fang
AU - Li, Peng
AU - Li, Wei
AU - Zhao, Ming Yu
AU - Xiong, Wei Wei
N1 - Publisher Copyright:
© 2018 Elsevier B.V.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - By using deep eutectic solvent mixture of ChCl (ChCl = choline chloride) and 1,8-diaminooctane as reaction medium, three new selenidostannates were synthesized, namely [Cr(en)3]2.5[SnSe4]·Cl3.5·(pip)0.5·1.5H2O (1) (en = ethylenediamine, pip = piperazine), [Ni(en)3][Sn3Se6.5(Se2)0.5] (2), and [Ni(en)3][Sn3Se7] (3). Compound 1 features a primary unit of SnSe4 tetrahedron, in which the [Cr(en)3]3+ complex acts as charge balance agent. In compound 2, there are two kinds of one dimensional chains, including [Sn3Se7]n2n– and [Sn3Se6(Se)2]n2n– anionic chains. The [Sn3Se7]n2n– chain is constructed by connecting [Sn3Se9] units via edge-sharing Se2- ion, while the [Sn3Se6(Se)2]n2n– chain is constructed by linking [Sn3Se10] units via sharing one Se2- ion and one Se22- ion. Compound 3 features a lamellar anionic [Sn3Se7]n2n– structure, where the [Ni(en)3]2+ ions are located in inter-lamellar space. The optical absorption spectra indicate band gaps of 2.23 eV for 1, 1.95 eV for 2, and 2.01 eV for 3.
AB - By using deep eutectic solvent mixture of ChCl (ChCl = choline chloride) and 1,8-diaminooctane as reaction medium, three new selenidostannates were synthesized, namely [Cr(en)3]2.5[SnSe4]·Cl3.5·(pip)0.5·1.5H2O (1) (en = ethylenediamine, pip = piperazine), [Ni(en)3][Sn3Se6.5(Se2)0.5] (2), and [Ni(en)3][Sn3Se7] (3). Compound 1 features a primary unit of SnSe4 tetrahedron, in which the [Cr(en)3]3+ complex acts as charge balance agent. In compound 2, there are two kinds of one dimensional chains, including [Sn3Se7]n2n– and [Sn3Se6(Se)2]n2n– anionic chains. The [Sn3Se7]n2n– chain is constructed by connecting [Sn3Se9] units via edge-sharing Se2- ion, while the [Sn3Se6(Se)2]n2n– chain is constructed by linking [Sn3Se10] units via sharing one Se2- ion and one Se22- ion. Compound 3 features a lamellar anionic [Sn3Se7]n2n– structure, where the [Ni(en)3]2+ ions are located in inter-lamellar space. The optical absorption spectra indicate band gaps of 2.23 eV for 1, 1.95 eV for 2, and 2.01 eV for 3.
KW - Chalcogenides
KW - Choline chloride
KW - Deep eutectic solvent
KW - Selenidostannates
UR - http://www.scopus.com/inward/record.url?scp=85053752878&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2018.09.046
DO - 10.1016/j.ica.2018.09.046
M3 - 文章
AN - SCOPUS:85053752878
SN - 0020-1693
VL - 484
SP - 214
EP - 218
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -