From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

Timur Islamoglu; Debmalya Ray; Peng Li; Marek B. Majewski; Isil Akpinar; Xuan Zhang; Christopher J. Cramer; Laura Gagliardi; Omar K. Farha

doi:10.1021/acs.inorgchem.8b01748

From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

Timur Islamoglu
, Debmalya Ray
, Peng Li
, Marek B. Majewski
, Isil Akpinar
, Xuan Zhang
, Christopher J. Cramer
, Laura Gagliardi
, Omar K. Farha

Northwestern University
University of Minnesota Twin Cities
King Abdulaziz University

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

Original language	English
Pages (from-to)	13246-13251
Number of pages	6
Journal	Inorganic Chemistry
Volume	57
Issue number	21
DOIs	https://doi.org/10.1021/acs.inorgchem.8b01748
State	Published - 5 Nov 2018
Externally published	Yes

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10.1021/acs.inorgchem.8b01748

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title = "From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks",

abstract = "Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.",

author = "Timur Islamoglu and Debmalya Ray and Peng Li and Majewski, \{Marek B.\} and Isil Akpinar and Xuan Zhang and Cramer, \{Christopher J.\} and Laura Gagliardi and Farha, \{Omar K.\}",

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doi = "10.1021/acs.inorgchem.8b01748",

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T2 - Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

AU - Islamoglu, Timur

AU - Ray, Debmalya

AU - Li, Peng

AU - Majewski, Marek B.

AU - Akpinar, Isil

AU - Zhang, Xuan

AU - Cramer, Christopher J.

AU - Gagliardi, Laura

AU - Farha, Omar K.

PY - 2018/11/5

Y1 - 2018/11/5

N2 - Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

AB - Isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O-H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

UR - https://www.scopus.com/pages/publications/85054826000

U2 - 10.1021/acs.inorgchem.8b01748

DO - 10.1021/acs.inorgchem.8b01748

M3 - 文章

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AN - SCOPUS:85054826000

SN - 0020-1669

VL - 57

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal-Organic Frameworks

Abstract

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