[Fe(SCN)2(bipy)2]·2(S8): A two-dimensional coordination polymer intercalating the S8 molecules

Min Ting Hao; Cheng Feng Du; Chong Bin Tian; Jian Rong Li; Xiao Ying Huang

doi:10.1016/j.inoche.2016.08.020

[Fe(SCN)₂(bipy)₂]·2(S₈): A two-dimensional coordination polymer intercalating the S₈ molecules

Min Ting Hao
, Cheng Feng Du
, Chong Bin Tian
, Jian Rong Li
, Xiao Ying Huang

Fujian Normal University
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A new coordination polymer compound [Fe(SCN)₂(bipy)₂]·2(S₈) (1) (bipy = 4,4′-bipyridine) has been synthesized by the reaction of the bifunctional ligand bipy, Fe(SCN)₂ and sulfur powder under hydrothermal conditions. The compound has been characterized by single and powder X-ray diffraction analysis, infrared spectroscopy and elemental analysis. Compound 1 features a two-dimensional layered structure with neutral S₈ molecules confined in between layers. The magnetic property studies of 1 indicated antiferromagnetic interactions.

Original language	English
Pages (from-to)	128-131
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	72
DOIs	https://doi.org/10.1016/j.inoche.2016.08.020
State	Published - 1 Oct 2016
Externally published	Yes

Keywords

Coordination polymer
Iron(II)
Layered structure
Magnetic properties
S molecules

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10.1016/j.inoche.2016.08.020

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title = "[Fe(SCN)2(bipy)2]·2(S8): A two-dimensional coordination polymer intercalating the S8 molecules",

abstract = "A new coordination polymer compound [Fe(SCN)2(bipy)2]·2(S8) (1) (bipy = 4,4′-bipyridine) has been synthesized by the reaction of the bifunctional ligand bipy, Fe(SCN)2 and sulfur powder under hydrothermal conditions. The compound has been characterized by single and powder X-ray diffraction analysis, infrared spectroscopy and elemental analysis. Compound 1 features a two-dimensional layered structure with neutral S8 molecules confined in between layers. The magnetic property studies of 1 indicated antiferromagnetic interactions.",

keywords = "Coordination polymer, Iron(II), Layered structure, Magnetic properties, S molecules",

author = "Hao, \{Min Ting\} and Du, \{Cheng Feng\} and Tian, \{Chong Bin\} and Li, \{Jian Rong\} and Huang, \{Xiao Ying\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = oct,

day = "1",

doi = "10.1016/j.inoche.2016.08.020",

language = "英语",

volume = "72",

pages = "128--131",

journal = "Inorganic Chemistry Communications",

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publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - [Fe(SCN)2(bipy)2]·2(S8)

T2 - A two-dimensional coordination polymer intercalating the S8 molecules

AU - Hao, Min Ting

AU - Du, Cheng Feng

AU - Tian, Chong Bin

AU - Li, Jian Rong

AU - Huang, Xiao Ying

PY - 2016/10/1

Y1 - 2016/10/1

N2 - A new coordination polymer compound [Fe(SCN)2(bipy)2]·2(S8) (1) (bipy = 4,4′-bipyridine) has been synthesized by the reaction of the bifunctional ligand bipy, Fe(SCN)2 and sulfur powder under hydrothermal conditions. The compound has been characterized by single and powder X-ray diffraction analysis, infrared spectroscopy and elemental analysis. Compound 1 features a two-dimensional layered structure with neutral S8 molecules confined in between layers. The magnetic property studies of 1 indicated antiferromagnetic interactions.

AB - A new coordination polymer compound [Fe(SCN)2(bipy)2]·2(S8) (1) (bipy = 4,4′-bipyridine) has been synthesized by the reaction of the bifunctional ligand bipy, Fe(SCN)2 and sulfur powder under hydrothermal conditions. The compound has been characterized by single and powder X-ray diffraction analysis, infrared spectroscopy and elemental analysis. Compound 1 features a two-dimensional layered structure with neutral S8 molecules confined in between layers. The magnetic property studies of 1 indicated antiferromagnetic interactions.

KW - Coordination polymer

KW - Iron(II)

KW - Layered structure

KW - Magnetic properties

KW - S molecules

UR - https://www.scopus.com/pages/publications/84984846920

U2 - 10.1016/j.inoche.2016.08.020

DO - 10.1016/j.inoche.2016.08.020

M3 - 文章

AN - SCOPUS:84984846920

SN - 1387-7003

VL - 72

SP - 128

EP - 131

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

[Fe(SCN)₂(bipy)₂]·2(S₈): A two-dimensional coordination polymer intercalating the S₈ molecules

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Keywords

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