Facile synthesis of mesoporouscobalt hexacyanoferrate nanocubes for high-performance supercapacitors

Mesoporous cobalt hexacyanoferrate nanocubes (meso–CoHCF) were prepared for the first time through a facile sacrificial template method. The CoHCF mesostructures possess a high specific surface area of 548.5 m²·g⁻¹ and a large amount of mesopores, which enable fast mass transport of electrolyte and abundant energy storage sites. When evaluated as supercapacitor materials, the meso–CoHCF materials exhibit a high specific capacitance of 285 F·g⁻¹, good rate capability and long cycle life with capacitance retention of 92.9% after 3000 cycles in Na₂SO₄ aqueous electrolyte. The excellent electrochemical properties demonstrate the rational preparation of mesoporous prussian blue and its analogues for energy storage applications.