Facile synthesis of LiCo1/3Ni1/3Mn1/3O2/Al(OH)3 composite as a high-performance cathode material for lithium ion cells

Chun Ping Hou; Yong Ma; Xiang Zhi Dong; Wang Chang Geng; Bao Liang Zhang; Qiu Yu Zhang

doi:10.1016/j.jallcom.2015.10.018

Facile synthesis of LiCo_1/3Ni_1/3Mn_1/3O₂/Al(OH)₃ composite as a high-performance cathode material for lithium ion cells

Chun Ping Hou, Yong Ma, Xiang Zhi Dong, Wang Chang Geng, Bao Liang Zhang, Qiu Yu Zhang

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A facile method for enhancing electrochemical performances of LiCo_1/3Ni_1/3Mn_1/3O₂ cathode material by mixing with Al(OH)₃ additives is reported. The commercial 18,650 size Li-ion cells were manufactured based on Al(OH)₃-mixed LiCo_1/3Ni_1/3Mn_1/3O₂ cathode and artificial graphite anode in a LiPF₆-based non-aqueous electrolyte. The cell with Al(OH)₃-mixed LiCo_1/3Ni_1/3Mn_1/3O₂ cathode exhibits an excellent capacity retention ratio of 63.1% after 300 cycles between 4.3 and 2.75 V at 55 °C, however, that of a pristine cell is only 29.7%. In contrast of the pristine cell, the storage stability of the Al(OH)₃-mixed LiCo_1/3Ni_1/3Mn_1/3O₂ cell is also enhanced greatly. It is found that reducing unwanted side-reactions on cathode with the electrolyte by adsorbing trace amounts of HF in the electrolyte lead to improvement in the electrochemical performances of Al(OH)₃-mixed LiCo_1/3Ni_1/3Mn_1/3O₂ cells.

Original language	English
Pages (from-to)	849-853
Number of pages	5
Journal	Journal of Alloys and Compounds
Volume	656
DOIs	https://doi.org/10.1016/j.jallcom.2015.10.018
State	Published - 25 Jan 2016

Keywords

Additive
Cathode material
Li-ion cell
Storage stability
Surface modification

Access to Document

10.1016/j.jallcom.2015.10.018

Cite this

@article{6df93fb6cf9b420f911bed84cbd6967c,

title = "Facile synthesis of LiCo1/3Ni1/3Mn1/3O2/Al(OH)3 composite as a high-performance cathode material for lithium ion cells",

abstract = "A facile method for enhancing electrochemical performances of LiCo1/3Ni1/3Mn1/3O2 cathode material by mixing with Al(OH)3 additives is reported. The commercial 18,650 size Li-ion cells were manufactured based on Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cathode and artificial graphite anode in a LiPF6-based non-aqueous electrolyte. The cell with Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cathode exhibits an excellent capacity retention ratio of 63.1% after 300 cycles between 4.3 and 2.75 V at 55 °C, however, that of a pristine cell is only 29.7%. In contrast of the pristine cell, the storage stability of the Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cell is also enhanced greatly. It is found that reducing unwanted side-reactions on cathode with the electrolyte by adsorbing trace amounts of HF in the electrolyte lead to improvement in the electrochemical performances of Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cells.",

keywords = "Additive, Cathode material, Li-ion cell, Storage stability, Surface modification",

author = "Hou, {Chun Ping} and Yong Ma and Dong, {Xiang Zhi} and Geng, {Wang Chang} and Zhang, {Bao Liang} and Zhang, {Qiu Yu}",

year = "2016",

month = jan,

day = "25",

doi = "10.1016/j.jallcom.2015.10.018",

language = "英语",

volume = "656",

pages = "849--853",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Facile synthesis of LiCo1/3Ni1/3Mn1/3O2/Al(OH)3 composite as a high-performance cathode material for lithium ion cells

AU - Hou, Chun Ping

AU - Ma, Yong

AU - Dong, Xiang Zhi

AU - Geng, Wang Chang

AU - Zhang, Bao Liang

AU - Zhang, Qiu Yu

PY - 2016/1/25

Y1 - 2016/1/25

N2 - A facile method for enhancing electrochemical performances of LiCo1/3Ni1/3Mn1/3O2 cathode material by mixing with Al(OH)3 additives is reported. The commercial 18,650 size Li-ion cells were manufactured based on Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cathode and artificial graphite anode in a LiPF6-based non-aqueous electrolyte. The cell with Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cathode exhibits an excellent capacity retention ratio of 63.1% after 300 cycles between 4.3 and 2.75 V at 55 °C, however, that of a pristine cell is only 29.7%. In contrast of the pristine cell, the storage stability of the Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cell is also enhanced greatly. It is found that reducing unwanted side-reactions on cathode with the electrolyte by adsorbing trace amounts of HF in the electrolyte lead to improvement in the electrochemical performances of Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cells.

AB - A facile method for enhancing electrochemical performances of LiCo1/3Ni1/3Mn1/3O2 cathode material by mixing with Al(OH)3 additives is reported. The commercial 18,650 size Li-ion cells were manufactured based on Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cathode and artificial graphite anode in a LiPF6-based non-aqueous electrolyte. The cell with Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cathode exhibits an excellent capacity retention ratio of 63.1% after 300 cycles between 4.3 and 2.75 V at 55 °C, however, that of a pristine cell is only 29.7%. In contrast of the pristine cell, the storage stability of the Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cell is also enhanced greatly. It is found that reducing unwanted side-reactions on cathode with the electrolyte by adsorbing trace amounts of HF in the electrolyte lead to improvement in the electrochemical performances of Al(OH)3-mixed LiCo1/3Ni1/3Mn1/3O2 cells.

KW - Additive

KW - Cathode material

KW - Li-ion cell

KW - Storage stability

KW - Surface modification

UR - http://www.scopus.com/inward/record.url?scp=84944789780&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2015.10.018

DO - 10.1016/j.jallcom.2015.10.018

M3 - 文章

AN - SCOPUS:84944789780

SN - 0925-8388

VL - 656

SP - 849

EP - 853

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Facile synthesis of LiCo_1/3Ni_1/3Mn_1/3O₂/Al(OH)₃ composite as a high-performance cathode material for lithium ion cells

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this