Facile synthesis and self-assembly of diazafluorenone-based p-n (donor-acceptor) organic semiconductors

  • Wei Jie Li
  • , Hai Mei Wu
  • , Yi Bao Li
  • , Chao Peng Hu
  • , Ming Dong Yi
  • , Ling Hai Xie
  • , Lin Chen
  • , Jian Feng Zhao
  • , Xiang Hua Zhao
  • , Nai En Shi
  • , Yan Qian
  • , Chen Wang
  • , Wei Wei
  • , Wei Huang

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

A mild and effective method to prepare 2,7-dibromo-4,5-diazafluoren-9-one (3) has been described involving tandem oxidation and rearrangement reactions. Diazafluorenone-based donor-acceptor (p-n) molecules via stille coupling reactions exhibit solvent-dependent fluorescence and excellent self-assembly behaviors at the solid-liquid interface according to the characterization of scanning tunneling microscopy (STM).

Original languageEnglish
Pages (from-to)8216-8221
Number of pages6
JournalTetrahedron
Volume68
Issue number39
DOIs
StatePublished - 30 Sep 2012
Externally publishedYes

Keywords

  • 2,7-Dibromo-4,5-diazafluoren-9-one
  • Organic semiconductors
  • Oxidation and rearrangement mechanism
  • P-n (donor-acceptor)
  • Self-assembly

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