Fabrication of a functional microgel-based hybrid nanofluid and its application in CO                         2                          gas adsorption

Dongdong Yao; Ting Li; Yaping Zheng; Zhilin Zhang

doi:10.1016/j.reactfunctpolym.2018.12.025

Fabrication of a functional microgel-based hybrid nanofluid and its application in CO ₂ gas adsorption

Dongdong Yao
, Ting Li
, Yaping Zheng
, Zhilin Zhang

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

In this study, a novel hybrid nanofluid, composed of a composite core of poly(2-dimethylamino ethyl methacrylate) microgel and silica (PDMAEMA/SiO ₂ ) and a shell of polyetheramine (M2070), was fabricated via a combination of inversed emulsion polymerization, biomimetic silicification and grafting onto approach. Firstly, PDMAEMA microgel of ca. 300-nm diameter with good dispersity was prepared in water/cyclohexane system. Subsequently, walnut kernel-structured and solid spherical PDMAEMA/SiO ₂ composites were fabricated using swollen and contractive PDMAEMA microgel as catalytic template, respectively. Then 3-(2, 3-epoxypropoxy) propyl trimethoxysilane (KH560) modified M2070 was grafted on PDMAEMA/SiO ₂ composites to obtain two kinds of solvent-free PDMAEMA/SiO ₂ @M2070 hybrid nanofluids with core@shell structure. Finally, the CO ₂ gas adsorption performance of these nanofluids was investigated under different CO ₂ pressure (0.5–4.5 MPa) at 25 °C. The results indicated that nanofluid with walnut kernel-structured core showed more excellent CO ₂ adsorption capacity than solid spherical one. Moreover, it still displayed good stability over ten adsorption-desorption cycles.

Original language	English
Pages (from-to)	131-137
Number of pages	7
Journal	Reactive and Functional Polymers
Volume	136
DOIs	https://doi.org/10.1016/j.reactfunctpolym.2018.12.025
State	Published - Mar 2019

Keywords

Biomimetic silicification
CO gas adsorption
PDMAEMA microgel
Solvent-free hybrid nanofluid

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10.1016/j.reactfunctpolym.2018.12.025

Cite this

@article{d1e59d82ba3d481694e18329472fa76f,

title = " Fabrication of a functional microgel-based hybrid nanofluid and its application in CO 2 gas adsorption ",

abstract = " In this study, a novel hybrid nanofluid, composed of a composite core of poly(2-dimethylamino ethyl methacrylate) microgel and silica (PDMAEMA/SiO 2 ) and a shell of polyetheramine (M2070), was fabricated via a combination of inversed emulsion polymerization, biomimetic silicification and grafting onto approach. Firstly, PDMAEMA microgel of ca. 300-nm diameter with good dispersity was prepared in water/cyclohexane system. Subsequently, walnut kernel-structured and solid spherical PDMAEMA/SiO 2 composites were fabricated using swollen and contractive PDMAEMA microgel as catalytic template, respectively. Then 3-(2, 3-epoxypropoxy) propyl trimethoxysilane (KH560) modified M2070 was grafted on PDMAEMA/SiO 2 composites to obtain two kinds of solvent-free PDMAEMA/SiO 2 @M2070 hybrid nanofluids with core@shell structure. Finally, the CO 2 gas adsorption performance of these nanofluids was investigated under different CO 2 pressure (0.5–4.5 MPa) at 25 °C. The results indicated that nanofluid with walnut kernel-structured core showed more excellent CO 2 adsorption capacity than solid spherical one. Moreover, it still displayed good stability over ten adsorption-desorption cycles.",

keywords = "Biomimetic silicification, CO gas adsorption, PDMAEMA microgel, Solvent-free hybrid nanofluid",

author = "Dongdong Yao and Ting Li and Yaping Zheng and Zhilin Zhang",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2019",

month = mar,

doi = "10.1016/j.reactfunctpolym.2018.12.025",

language = "英语",

volume = "136",

pages = "131--137",

journal = "Reactive and Functional Polymers",

issn = "1381-5148",

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}

Fabrication of a functional microgel-based hybrid nanofluid and its application in CO ₂ gas adsorption . / Yao, Dongdong; Li, Ting; Zheng, Yaping et al.
In: Reactive and Functional Polymers, Vol. 136, 03.2019, p. 131-137.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Fabrication of a functional microgel-based hybrid nanofluid and its application in CO 2 gas adsorption

AU - Yao, Dongdong

AU - Li, Ting

AU - Zheng, Yaping

AU - Zhang, Zhilin

PY - 2019/3

Y1 - 2019/3

N2 - In this study, a novel hybrid nanofluid, composed of a composite core of poly(2-dimethylamino ethyl methacrylate) microgel and silica (PDMAEMA/SiO 2 ) and a shell of polyetheramine (M2070), was fabricated via a combination of inversed emulsion polymerization, biomimetic silicification and grafting onto approach. Firstly, PDMAEMA microgel of ca. 300-nm diameter with good dispersity was prepared in water/cyclohexane system. Subsequently, walnut kernel-structured and solid spherical PDMAEMA/SiO 2 composites were fabricated using swollen and contractive PDMAEMA microgel as catalytic template, respectively. Then 3-(2, 3-epoxypropoxy) propyl trimethoxysilane (KH560) modified M2070 was grafted on PDMAEMA/SiO 2 composites to obtain two kinds of solvent-free PDMAEMA/SiO 2 @M2070 hybrid nanofluids with core@shell structure. Finally, the CO 2 gas adsorption performance of these nanofluids was investigated under different CO 2 pressure (0.5–4.5 MPa) at 25 °C. The results indicated that nanofluid with walnut kernel-structured core showed more excellent CO 2 adsorption capacity than solid spherical one. Moreover, it still displayed good stability over ten adsorption-desorption cycles.

AB - In this study, a novel hybrid nanofluid, composed of a composite core of poly(2-dimethylamino ethyl methacrylate) microgel and silica (PDMAEMA/SiO 2 ) and a shell of polyetheramine (M2070), was fabricated via a combination of inversed emulsion polymerization, biomimetic silicification and grafting onto approach. Firstly, PDMAEMA microgel of ca. 300-nm diameter with good dispersity was prepared in water/cyclohexane system. Subsequently, walnut kernel-structured and solid spherical PDMAEMA/SiO 2 composites were fabricated using swollen and contractive PDMAEMA microgel as catalytic template, respectively. Then 3-(2, 3-epoxypropoxy) propyl trimethoxysilane (KH560) modified M2070 was grafted on PDMAEMA/SiO 2 composites to obtain two kinds of solvent-free PDMAEMA/SiO 2 @M2070 hybrid nanofluids with core@shell structure. Finally, the CO 2 gas adsorption performance of these nanofluids was investigated under different CO 2 pressure (0.5–4.5 MPa) at 25 °C. The results indicated that nanofluid with walnut kernel-structured core showed more excellent CO 2 adsorption capacity than solid spherical one. Moreover, it still displayed good stability over ten adsorption-desorption cycles.

KW - Biomimetic silicification

KW - CO gas adsorption

KW - PDMAEMA microgel

KW - Solvent-free hybrid nanofluid

UR - https://www.scopus.com/pages/publications/85060109031

U2 - 10.1016/j.reactfunctpolym.2018.12.025

DO - 10.1016/j.reactfunctpolym.2018.12.025

M3 - 文章

AN - SCOPUS:85060109031

SN - 1381-5148

VL - 136

SP - 131

EP - 137

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

ER -

Fabrication of a functional microgel-based hybrid nanofluid and its application in CO ₂ gas adsorption

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Keywords

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