(enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: Two thioarsenates(iii, v) with mixed-valent optical properties

Ke Zhao Du; Mei Ling Feng; Xing Hui Qi; Zu Ju Ma; Long Hua Li; Jian Rong Li; Cheng Feng Du; Guo Dong Zou; Xiao Ying Huang

doi:10.1039/c3dt53048e

(enH₂)_4.5[In(As^VS₄) ₃][As₂^III(μ-S₂)S₃]Cl and (enH₂)MnAs^IIIAs^VS₆: Two thioarsenates(iii, v) with mixed-valent optical properties

Ke Zhao Du
, Mei Ling Feng
, Xing Hui Qi
, Zu Ju Ma
, Long Hua Li
, Jian Rong Li
, Cheng Feng Du
, Guo Dong Zou
, Xiao Ying Huang

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Two mixed-valent thioarsenates, namely (enH₂) _4.5[In(As^VS₄)₃][As₂ ^III(μ-S₂)S₃]Cl (1) and (enH ₂)MnAs^IIIAs^VS₆ (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

Original language	English
Pages (from-to)	2733-2736
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	7
DOIs	https://doi.org/10.1039/c3dt53048e
State	Published - 21 Feb 2014
Externally published	Yes

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title = "(enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: Two thioarsenates(iii, v) with mixed-valent optical properties",

abstract = "Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.",

author = "Du, \{Ke Zhao\} and Feng, \{Mei Ling\} and Qi, \{Xing Hui\} and Ma, \{Zu Ju\} and Li, \{Long Hua\} and Li, \{Jian Rong\} and Du, \{Cheng Feng\} and Zou, \{Guo Dong\} and Huang, \{Xiao Ying\}",

year = "2014",

month = feb,

day = "21",

doi = "10.1039/c3dt53048e",

language = "英语",

volume = "43",

pages = "2733--2736",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - (enH2)4.5[In(AsVS4) 3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6

T2 - Two thioarsenates(iii, v) with mixed-valent optical properties

AU - Du, Ke Zhao

AU - Feng, Mei Ling

AU - Qi, Xing Hui

AU - Ma, Zu Ju

AU - Li, Long Hua

AU - Li, Jian Rong

AU - Du, Cheng Feng

AU - Zou, Guo Dong

AU - Huang, Xiao Ying

PY - 2014/2/21

Y1 - 2014/2/21

N2 - Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

AB - Two mixed-valent thioarsenates, namely (enH2) 4.5[In(AsVS4)3][As2 III(μ-S2)S3]Cl (1) and (enH 2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

UR - https://www.scopus.com/pages/publications/84892921268

U2 - 10.1039/c3dt53048e

DO - 10.1039/c3dt53048e

M3 - 文章

AN - SCOPUS:84892921268

SN - 1477-9226

VL - 43

SP - 2733

EP - 2736

JO - Dalton Transactions

JF - Dalton Transactions

IS - 7

ER -

(enH₂)_4.5[In(As^VS₄) ₃][As₂^III(μ-S₂)S₃]Cl and (enH₂)MnAs^IIIAs^VS₆: Two thioarsenates(iii, v) with mixed-valent optical properties

Abstract

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