Effects of Weak Hydrogen-Bonding Interactions on Supramolecular Assemblies of N,N-Dimethyl-1-admantylamine

Cheng Long Yi; Fu Chen; Shi Wang; Yong Hua Li; Wei Huang

doi:10.1007/s10870-018-0712-8

Effects of Weak Hydrogen-Bonding Interactions on Supramolecular Assemblies of N,N-Dimethyl-1-admantylamine

Cheng Long Yi
, Fu Chen
, Shi Wang
, Yong Hua Li
, Wei Huang

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Abstract: The reaction of N,N-dimethyl-1-admantylamine (ada) and inorganic acids or trivalent metal chlorides in the hydrochloric acid medium yields four new supramolecular salts, i.e. (adaH⁺)₃·(SbCl₃)·(SbCl₄ ⁻)·(SbCl₅ ²⁻) (1), (adaH⁺)·(FeCl₄ ⁻) (2), (adaH⁺)·(ClO₄ ⁻) (3), and (adaH⁺)·(I₃ ⁻) (4), respectively. Compound 5, (dtaH⁺)₂·(I₃ ⁻)·I⁻ (dta = N,N-dimethyl-2,4,6-trimethylaniline) was also prepared for comparison with 4. Structural analyses reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonded chain structures are observed in 1, and discrete structures are observed in 2, 4 and 5. Surprisingly, due to the coexistence of SbCl₃, [SbCl₄]⁻ and [SbCl₅]²⁻, compound 1 proves to be a unique example according to the Cambridge Structure Database (CSD). Graphical Abstract: Structural analysis reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonding chain structures are observed in 1 and discrete structures are observed in 2, 4 and 5. [Figure not available: see fulltext.].

Original language	English
Pages (from-to)	54-63
Number of pages	10
Journal	Journal of Chemical Crystallography
Volume	48
Issue number	1-2
DOIs	https://doi.org/10.1007/s10870-018-0712-8
State	Published - 1 Jun 2018
Externally published	Yes

Keywords

N,N-Dimethyl-1-admantylamine
Supramolecular salts
Weak hydrogen bonds

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10.1007/s10870-018-0712-8

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@article{f5d94a7132b94536a688eb15242f6c90,

title = "Effects of Weak Hydrogen-Bonding Interactions on Supramolecular Assemblies of N,N-Dimethyl-1-admantylamine",

abstract = "Abstract: The reaction of N,N-dimethyl-1-admantylamine (ada) and inorganic acids or trivalent metal chlorides in the hydrochloric acid medium yields four new supramolecular salts, i.e. (adaH+)3·(SbCl3)·(SbCl4 −)·(SbCl5 2−) (1), (adaH+)·(FeCl4 −) (2), (adaH+)·(ClO4 −) (3), and (adaH+)·(I3 −) (4), respectively. Compound 5, (dtaH+)2·(I3 −)·I− (dta = N,N-dimethyl-2,4,6-trimethylaniline) was also prepared for comparison with 4. Structural analyses reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonded chain structures are observed in 1, and discrete structures are observed in 2, 4 and 5. Surprisingly, due to the coexistence of SbCl3, [SbCl4]− and [SbCl5]2−, compound 1 proves to be a unique example according to the Cambridge Structure Database (CSD). Graphical Abstract: Structural analysis reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonding chain structures are observed in 1 and discrete structures are observed in 2, 4 and 5. [Figure not available: see fulltext.].",

keywords = "N,N-Dimethyl-1-admantylamine, Supramolecular salts, Weak hydrogen bonds",

author = "Yi, \{Cheng Long\} and Fu Chen and Shi Wang and Li, \{Yong Hua\} and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2018, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2018",

month = jun,

day = "1",

doi = "10.1007/s10870-018-0712-8",

language = "英语",

volume = "48",

pages = "54--63",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer",

number = "1-2",

}

TY - JOUR

T1 - Effects of Weak Hydrogen-Bonding Interactions on Supramolecular Assemblies of N,N-Dimethyl-1-admantylamine

AU - Yi, Cheng Long

AU - Chen, Fu

AU - Wang, Shi

AU - Li, Yong Hua

AU - Huang, Wei

PY - 2018/6/1

Y1 - 2018/6/1

N2 - Abstract: The reaction of N,N-dimethyl-1-admantylamine (ada) and inorganic acids or trivalent metal chlorides in the hydrochloric acid medium yields four new supramolecular salts, i.e. (adaH+)3·(SbCl3)·(SbCl4 −)·(SbCl5 2−) (1), (adaH+)·(FeCl4 −) (2), (adaH+)·(ClO4 −) (3), and (adaH+)·(I3 −) (4), respectively. Compound 5, (dtaH+)2·(I3 −)·I− (dta = N,N-dimethyl-2,4,6-trimethylaniline) was also prepared for comparison with 4. Structural analyses reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonded chain structures are observed in 1, and discrete structures are observed in 2, 4 and 5. Surprisingly, due to the coexistence of SbCl3, [SbCl4]− and [SbCl5]2−, compound 1 proves to be a unique example according to the Cambridge Structure Database (CSD). Graphical Abstract: Structural analysis reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonding chain structures are observed in 1 and discrete structures are observed in 2, 4 and 5. [Figure not available: see fulltext.].

AB - Abstract: The reaction of N,N-dimethyl-1-admantylamine (ada) and inorganic acids or trivalent metal chlorides in the hydrochloric acid medium yields four new supramolecular salts, i.e. (adaH+)3·(SbCl3)·(SbCl4 −)·(SbCl5 2−) (1), (adaH+)·(FeCl4 −) (2), (adaH+)·(ClO4 −) (3), and (adaH+)·(I3 −) (4), respectively. Compound 5, (dtaH+)2·(I3 −)·I− (dta = N,N-dimethyl-2,4,6-trimethylaniline) was also prepared for comparison with 4. Structural analyses reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonded chain structures are observed in 1, and discrete structures are observed in 2, 4 and 5. Surprisingly, due to the coexistence of SbCl3, [SbCl4]− and [SbCl5]2−, compound 1 proves to be a unique example according to the Cambridge Structure Database (CSD). Graphical Abstract: Structural analysis reveals that the weak hydrogen-bonding interactions play a crucial role in the formation of various hydrogen-bonding networks. 3D supramolecular architectures are observed in 3, independent 1D infinite hydrogen-bonding chain structures are observed in 1 and discrete structures are observed in 2, 4 and 5. [Figure not available: see fulltext.].

KW - N,N-Dimethyl-1-admantylamine

KW - Supramolecular salts

KW - Weak hydrogen bonds

UR - https://www.scopus.com/pages/publications/85046035878

U2 - 10.1007/s10870-018-0712-8

DO - 10.1007/s10870-018-0712-8

M3 - 文章

AN - SCOPUS:85046035878

SN - 1074-1542

VL - 48

SP - 54

EP - 63

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 1-2

ER -

Effects of Weak Hydrogen-Bonding Interactions on Supramolecular Assemblies of N,N-Dimethyl-1-admantylamine

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