Effect of novel phosphazene-type additives on the tribological properties of Z-DOL in a steel-on-steel contact

Jiamei Zhu; Yongmin Liang; Weimin Liu

doi:10.1016/j.triboint.2003.11.003

Effect of novel phosphazene-type additives on the tribological properties of Z-DOL in a steel-on-steel contact

Jiamei Zhu
, Yongmin Liang
, Weimin Liu

CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The effect of hexakis(1,1,5-trihydroperfluoropentoxy)cyclotriphosphazene (X-100) and a novel synthetic bridged alkoxycyclotriphosphazene (denoted LA-2P) as additives in Z-DOL, a perfluoropolyether-type lubricant, on the friction and wear behavior of a steel-on-steel system was investigated. Thus, the friction and wear test of a steel disc sliding against the same steel counterpart ball was carried out on an SRV oscillating friction and wear tester. The chemical features of the worn steel surfaces were analyzed by means of X-ray photoelectron spectroscopy. The results indicate that both additives are effective in improving the tribological performance of Z-DOL and in preventing its catalytic decomposition. Z-DOL/LA-2P shows the best anti-wear ability. Moreover, both additives also increase the thermal stability of Z-DOL in the presence of AlCl₃ as a catalyst. In particular, the Z-DOL/LA-2P mixture shows the highest complete thermal degradation temperature.

Original language	English
Pages (from-to)	333-337
Number of pages	5
Journal	Tribology International
Volume	37
Issue number	4
DOIs	https://doi.org/10.1016/j.triboint.2003.11.003
State	Published - Apr 2004
Externally published	Yes

Keywords

Additives
Phosphazene
Thermal stability
Tribological properties

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10.1016/j.triboint.2003.11.003

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@article{8a8e2d2240434e66a3dd01d2193f012f,

title = "Effect of novel phosphazene-type additives on the tribological properties of Z-DOL in a steel-on-steel contact",

abstract = "The effect of hexakis(1,1,5-trihydroperfluoropentoxy)cyclotriphosphazene (X-100) and a novel synthetic bridged alkoxycyclotriphosphazene (denoted LA-2P) as additives in Z-DOL, a perfluoropolyether-type lubricant, on the friction and wear behavior of a steel-on-steel system was investigated. Thus, the friction and wear test of a steel disc sliding against the same steel counterpart ball was carried out on an SRV oscillating friction and wear tester. The chemical features of the worn steel surfaces were analyzed by means of X-ray photoelectron spectroscopy. The results indicate that both additives are effective in improving the tribological performance of Z-DOL and in preventing its catalytic decomposition. Z-DOL/LA-2P shows the best anti-wear ability. Moreover, both additives also increase the thermal stability of Z-DOL in the presence of AlCl3 as a catalyst. In particular, the Z-DOL/LA-2P mixture shows the highest complete thermal degradation temperature.",

keywords = "Additives, Phosphazene, Thermal stability, Tribological properties",

author = "Jiamei Zhu and Yongmin Liang and Weimin Liu",

year = "2004",

month = apr,

doi = "10.1016/j.triboint.2003.11.003",

language = "英语",

volume = "37",

pages = "333--337",

journal = "Tribology International",

issn = "0301-679X",

publisher = "Elsevier Inc.",

number = "4",

}

TY - JOUR

T1 - Effect of novel phosphazene-type additives on the tribological properties of Z-DOL in a steel-on-steel contact

AU - Zhu, Jiamei

AU - Liang, Yongmin

AU - Liu, Weimin

PY - 2004/4

Y1 - 2004/4

N2 - The effect of hexakis(1,1,5-trihydroperfluoropentoxy)cyclotriphosphazene (X-100) and a novel synthetic bridged alkoxycyclotriphosphazene (denoted LA-2P) as additives in Z-DOL, a perfluoropolyether-type lubricant, on the friction and wear behavior of a steel-on-steel system was investigated. Thus, the friction and wear test of a steel disc sliding against the same steel counterpart ball was carried out on an SRV oscillating friction and wear tester. The chemical features of the worn steel surfaces were analyzed by means of X-ray photoelectron spectroscopy. The results indicate that both additives are effective in improving the tribological performance of Z-DOL and in preventing its catalytic decomposition. Z-DOL/LA-2P shows the best anti-wear ability. Moreover, both additives also increase the thermal stability of Z-DOL in the presence of AlCl3 as a catalyst. In particular, the Z-DOL/LA-2P mixture shows the highest complete thermal degradation temperature.

AB - The effect of hexakis(1,1,5-trihydroperfluoropentoxy)cyclotriphosphazene (X-100) and a novel synthetic bridged alkoxycyclotriphosphazene (denoted LA-2P) as additives in Z-DOL, a perfluoropolyether-type lubricant, on the friction and wear behavior of a steel-on-steel system was investigated. Thus, the friction and wear test of a steel disc sliding against the same steel counterpart ball was carried out on an SRV oscillating friction and wear tester. The chemical features of the worn steel surfaces were analyzed by means of X-ray photoelectron spectroscopy. The results indicate that both additives are effective in improving the tribological performance of Z-DOL and in preventing its catalytic decomposition. Z-DOL/LA-2P shows the best anti-wear ability. Moreover, both additives also increase the thermal stability of Z-DOL in the presence of AlCl3 as a catalyst. In particular, the Z-DOL/LA-2P mixture shows the highest complete thermal degradation temperature.

KW - Additives

KW - Phosphazene

KW - Thermal stability

KW - Tribological properties

UR - https://www.scopus.com/pages/publications/0942279396

U2 - 10.1016/j.triboint.2003.11.003

DO - 10.1016/j.triboint.2003.11.003

M3 - 文章

AN - SCOPUS:0942279396

SN - 0301-679X

VL - 37

SP - 333

EP - 337

JO - Tribology International

JF - Tribology International

IS - 4

ER -

Effect of novel phosphazene-type additives on the tribological properties of Z-DOL in a steel-on-steel contact

Abstract

Keywords

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