Doped Manipulation of Photoluminescence and Carrier Lifetime from CH                         3                         NH                         3                         PbI                         3                          Perovskite Thin Films

Lixia Ren; Min Wang; Shuanhu Wang; Hong Yan; Zhan Zhang; Ming Li; Zhaoting Zhang; Kexin Jin

doi:10.1021/acsami.9b01506

Doped Manipulation of Photoluminescence and Carrier Lifetime from CH ₃ NH ₃ PbI ₃ Perovskite Thin Films

Lixia Ren
, Min Wang
, Shuanhu Wang
, Hong Yan
, Zhan Zhang
, Ming Li
, Zhaoting Zhang
, Kexin Jin

School of Physical Science and Technology

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The compositional doping techniques can delicately tune the band gap, carrier concentration, and mobility of perovskites to optimize the photoelectric properties of materials. It is reported that the doped perovskites have been widely researched in the photovoltaic and photoelectronic field. Here, we show that the photoluminescence intensity and carrier lifetime of CH ₃ NH ₃ PbI ₃ films have been improved by 3 orders of magnitude by incorporating abundant MnAc ₂ ·4H ₂ O in the perovskite precursor solution, which benefits from the morphological change and surface passivation induced by hydration water and surface manganese acetate. We also witness the increased photoluminescence quantum yield for film and the changed power conversion efficiency for perovskite solar cells. More importantly, the enhanced chemical stability of perovskite is displayed by immersing films into the water.

Original language	English
Pages (from-to)	16174-16180
Number of pages	7
Journal	ACS Applied Materials and Interfaces
Volume	11
Issue number	17
DOIs	https://doi.org/10.1021/acsami.9b01506
State	Published - 1 May 2019

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

carrier lifetime
MnAc insertion
perovskite
photoluminescence
surface passivation

Access to Document

10.1021/acsami.9b01506

Cite this

Ren, L., Wang, M., Wang, S., Yan, H., Zhang, Z., Li, M., Zhang, Z., & Jin, K. (2019). Doped Manipulation of Photoluminescence and Carrier Lifetime from CH ₃ NH ₃ PbI ₃ Perovskite Thin Films ACS Applied Materials and Interfaces, 11(17), 16174-16180. https://doi.org/10.1021/acsami.9b01506

Ren, Lixia ; Wang, Min ; Wang, Shuanhu et al. / Doped Manipulation of Photoluminescence and Carrier Lifetime from CH ₃ NH ₃ PbI ₃ Perovskite Thin Films In: ACS Applied Materials and Interfaces. 2019 ; Vol. 11, No. 17. pp. 16174-16180.

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abstract = " The compositional doping techniques can delicately tune the band gap, carrier concentration, and mobility of perovskites to optimize the photoelectric properties of materials. It is reported that the doped perovskites have been widely researched in the photovoltaic and photoelectronic field. Here, we show that the photoluminescence intensity and carrier lifetime of CH 3 NH 3 PbI 3 films have been improved by 3 orders of magnitude by incorporating abundant MnAc 2 ·4H 2 O in the perovskite precursor solution, which benefits from the morphological change and surface passivation induced by hydration water and surface manganese acetate. We also witness the increased photoluminescence quantum yield for film and the changed power conversion efficiency for perovskite solar cells. More importantly, the enhanced chemical stability of perovskite is displayed by immersing films into the water.",

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Ren, L, Wang, M, Wang, S, Yan, H, Zhang, Z, Li, M, Zhang, Z & Jin, K 2019, ' Doped Manipulation of Photoluminescence and Carrier Lifetime from CH ₃ NH ₃ PbI ₃ Perovskite Thin Films ', ACS Applied Materials and Interfaces, vol. 11, no. 17, pp. 16174-16180. https://doi.org/10.1021/acsami.9b01506

Doped Manipulation of Photoluminescence and Carrier Lifetime from CH ₃ NH ₃ PbI ₃ Perovskite Thin Films . / Ren, Lixia; Wang, Min; Wang, Shuanhu et al.
In: ACS Applied Materials and Interfaces, Vol. 11, No. 17, 01.05.2019, p. 16174-16180.

Research output: Contribution to journal › Article › peer-review

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AU - Ren, Lixia

AU - Wang, Min

AU - Wang, Shuanhu

AU - Yan, Hong

AU - Zhang, Zhan

AU - Li, Ming

AU - Zhang, Zhaoting

AU - Jin, Kexin

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AB - The compositional doping techniques can delicately tune the band gap, carrier concentration, and mobility of perovskites to optimize the photoelectric properties of materials. It is reported that the doped perovskites have been widely researched in the photovoltaic and photoelectronic field. Here, we show that the photoluminescence intensity and carrier lifetime of CH 3 NH 3 PbI 3 films have been improved by 3 orders of magnitude by incorporating abundant MnAc 2 ·4H 2 O in the perovskite precursor solution, which benefits from the morphological change and surface passivation induced by hydration water and surface manganese acetate. We also witness the increased photoluminescence quantum yield for film and the changed power conversion efficiency for perovskite solar cells. More importantly, the enhanced chemical stability of perovskite is displayed by immersing films into the water.

KW - carrier lifetime

KW - MnAc insertion

KW - perovskite

KW - photoluminescence

KW - surface passivation

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Ren L, Wang M, Wang S, Yan H, Zhang Z, Li M et al. Doped Manipulation of Photoluminescence and Carrier Lifetime from CH ₃ NH ₃ PbI ₃ Perovskite Thin Films ACS Applied Materials and Interfaces. 2019 May 1;11(17):16174-16180. doi: 10.1021/acsami.9b01506