Abstract
The directional solidification of highly undercooled eutectic Ni 78.6Si21.4 alloy is firstly achieved. In contrast with the conventional solidification, it occurs under a negative gradient at the solid/liquid interface. The essential condition for the processing is that the thermal diffusion in liquid plays a dominant role in the crystal growth. A directional solidification Ni3Si dendrite structure is obtained at the undercooling of 72 K. The other directional solidification a-Ni dendrite is derived at the undercooling of 195 K. Thermodynamic modeling of homogeneous nucleation is applied in undercooled eutectic Ni78.6Si21.4 alloy. It is found that Ni3Si is easier nucleation than a-Ni in undercooled eutectic Ni78.6Si21.4 melt. Calculated dendrite growth velocities confirm the predicted tendency of dendrite growth on the foundation of LKT/BCT theories.
| Original language | English |
|---|---|
| Pages (from-to) | 1558-1562 |
| Number of pages | 5 |
| Journal | Materials Letters |
| Volume | 59 |
| Issue number | 12 |
| DOIs | |
| State | Published - May 2005 |
Keywords
- Diffusion
- Eutectic alloy
- High undercooling
- Solidification