Directional solidification of highly undercooled eutectic Ni 78.6Si21.4 alloy

  • Yiping Lu
  • , Gencang Yang
  • , Zengzhe Xi
  • , Haipeng Wang
  • , Yaohe Zhou

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The directional solidification of highly undercooled eutectic Ni 78.6Si21.4 alloy is firstly achieved. In contrast with the conventional solidification, it occurs under a negative gradient at the solid/liquid interface. The essential condition for the processing is that the thermal diffusion in liquid plays a dominant role in the crystal growth. A directional solidification Ni3Si dendrite structure is obtained at the undercooling of 72 K. The other directional solidification a-Ni dendrite is derived at the undercooling of 195 K. Thermodynamic modeling of homogeneous nucleation is applied in undercooled eutectic Ni78.6Si21.4 alloy. It is found that Ni3Si is easier nucleation than a-Ni in undercooled eutectic Ni78.6Si21.4 melt. Calculated dendrite growth velocities confirm the predicted tendency of dendrite growth on the foundation of LKT/BCT theories.

Original languageEnglish
Pages (from-to)1558-1562
Number of pages5
JournalMaterials Letters
Volume59
Issue number12
DOIs
StatePublished - May 2005

Keywords

  • Diffusion
  • Eutectic alloy
  • High undercooling
  • Solidification

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