Diffusion behavior of Ni in Zr48Cu36Ag8Al8 bulk metallic glass within supercooled liquid region

Lin Lin Sun; Jun Wang; Hong Chao Kou; Bin Tang; Jin Shan Li; Ping Xiang Zhang

doi:10.1016/S1003-6326(15)63712-8

Diffusion behavior of Ni in Zr₄₈Cu₃₆Ag₈Al₈ bulk metallic glass within supercooled liquid region

Lin Lin Sun, Jun Wang, Hong Chao Kou, Bin Tang, Jin Shan Li, Ping Xiang Zhang

School of Materials Sience and Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Abstract Diffusion behavior of Ni in Zr₄₈Cu₃₆Ag₈Al₈ metallic glass was investigated in the temperature range of 683-723 K by secondary ion mass spectrum (SIMS) and transmission electron microscope (TEM). The diffusivity of Ni in Zr₄₈Cu₃₆Ag₈Al₈ is reasonably fitted by a single Arrhenius relation with small effective activation energy. The diffusivity of Ni in Zr₄₈Cu₃₆Ag₈Al₈ is an instantaneous function of annealing time in the supercooled liquid region. In addition, a large number of nano-crystals are detected near the interface of Ni-Zr₄₈Cu₃₆Ag₈Al₈ diffusion couple, and its width is broader than the Ni diffusion depth determined by SIMS. The results indicate that atomic inter-diffusion is an important factor to promote the formation of nano-crystals within the diffusion zone.

Original language	English
Article number	63712
Pages (from-to)	1171-1175
Number of pages	5
Journal	Transactions of Nonferrous Metals Society of China (English Edition)
Volume	25
Issue number	4
DOIs	https://doi.org/10.1016/S1003-6326(15)63712-8
State	Published - 1 Apr 2015

Keywords

diffusion behavior
interface
metallic glasses
nano-crystal

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10.1016/S1003-6326(15)63712-8

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title = "Diffusion behavior of Ni in Zr48Cu36Ag8Al8 bulk metallic glass within supercooled liquid region",

abstract = "Abstract Diffusion behavior of Ni in Zr48Cu36Ag8Al8 metallic glass was investigated in the temperature range of 683-723 K by secondary ion mass spectrum (SIMS) and transmission electron microscope (TEM). The diffusivity of Ni in Zr48Cu36Ag8Al8 is reasonably fitted by a single Arrhenius relation with small effective activation energy. The diffusivity of Ni in Zr48Cu36Ag8Al8 is an instantaneous function of annealing time in the supercooled liquid region. In addition, a large number of nano-crystals are detected near the interface of Ni-Zr48Cu36Ag8Al8 diffusion couple, and its width is broader than the Ni diffusion depth determined by SIMS. The results indicate that atomic inter-diffusion is an important factor to promote the formation of nano-crystals within the diffusion zone.",

keywords = "diffusion behavior, interface, metallic glasses, nano-crystal",

author = "Sun, {Lin Lin} and Jun Wang and Kou, {Hong Chao} and Bin Tang and Li, {Jin Shan} and Zhang, {Ping Xiang}",

note = "Publisher Copyright: {\textcopyright} 2015 The Nonferrous Metals Society of China.",

year = "2015",

month = apr,

day = "1",

doi = "10.1016/S1003-6326(15)63712-8",

language = "英语",

volume = "25",

pages = "1171--1175",

journal = "Transactions of Nonferrous Metals Society of China (English Edition)",

issn = "1003-6326",

publisher = "Nonferrous Metals Society of China",

number = "4",

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TY - JOUR

T1 - Diffusion behavior of Ni in Zr48Cu36Ag8Al8 bulk metallic glass within supercooled liquid region

AU - Sun, Lin Lin

AU - Wang, Jun

AU - Kou, Hong Chao

AU - Tang, Bin

AU - Li, Jin Shan

AU - Zhang, Ping Xiang

PY - 2015/4/1

Y1 - 2015/4/1

N2 - Abstract Diffusion behavior of Ni in Zr48Cu36Ag8Al8 metallic glass was investigated in the temperature range of 683-723 K by secondary ion mass spectrum (SIMS) and transmission electron microscope (TEM). The diffusivity of Ni in Zr48Cu36Ag8Al8 is reasonably fitted by a single Arrhenius relation with small effective activation energy. The diffusivity of Ni in Zr48Cu36Ag8Al8 is an instantaneous function of annealing time in the supercooled liquid region. In addition, a large number of nano-crystals are detected near the interface of Ni-Zr48Cu36Ag8Al8 diffusion couple, and its width is broader than the Ni diffusion depth determined by SIMS. The results indicate that atomic inter-diffusion is an important factor to promote the formation of nano-crystals within the diffusion zone.

AB - Abstract Diffusion behavior of Ni in Zr48Cu36Ag8Al8 metallic glass was investigated in the temperature range of 683-723 K by secondary ion mass spectrum (SIMS) and transmission electron microscope (TEM). The diffusivity of Ni in Zr48Cu36Ag8Al8 is reasonably fitted by a single Arrhenius relation with small effective activation energy. The diffusivity of Ni in Zr48Cu36Ag8Al8 is an instantaneous function of annealing time in the supercooled liquid region. In addition, a large number of nano-crystals are detected near the interface of Ni-Zr48Cu36Ag8Al8 diffusion couple, and its width is broader than the Ni diffusion depth determined by SIMS. The results indicate that atomic inter-diffusion is an important factor to promote the formation of nano-crystals within the diffusion zone.

KW - diffusion behavior

KW - interface

KW - metallic glasses

KW - nano-crystal

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U2 - 10.1016/S1003-6326(15)63712-8

DO - 10.1016/S1003-6326(15)63712-8

M3 - 文章

AN - SCOPUS:84929168933

SN - 1003-6326

VL - 25

SP - 1171

EP - 1175

JO - Transactions of Nonferrous Metals Society of China (English Edition)

JF - Transactions of Nonferrous Metals Society of China (English Edition)

IS - 4

M1 - 63712

ER -

Diffusion behavior of Ni in Zr₄₈Cu₃₆Ag₈Al₈ bulk metallic glass within supercooled liquid region

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