Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C

Xinyu Meng; Yujie Ma; Chun Guo; Bo Chen; Shaobo Yang; Juanli Deng; Shangwu Fan

doi:10.1016/j.jeurceramsoc.2024.05.043

Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C

Xinyu Meng
, Yujie Ma
, Chun Guo
, Bo Chen
, Shaobo Yang
, Juanli Deng
, Shangwu Fan

School of Materials Sience and Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The intrinsic characteristics of Yb₂O₃-Al₂O₃-SiO₂ (YbAS) glass-ceramics and their resistance to corrosion by molten calcium magnesium aluminosilicate (CMAS) at 1350 °C were systematically investigated. YbAS glass-ceramics, characterized by diverse compositions, maintaining phase stability over extended durations at elevated temperatures. After CMAS corrosion for 50 h, the main reaction phases were CaAl₂Si₂O₈ and Ca₂Yb₈(SiO₄)₆O₂, accompanied by multiple ion solid solution garnet in certain components. The glass component positioned along the eutectic line of Yb₂Si₂O₇ and mullite, with an OB value marginally exceeding that of CMAS, exhibits superior corrosion resistance to CMAS. This finding offers valuable insights for the subsequent design of environmental barrier coatings (EBCs).

Original language	English
Pages (from-to)	7891-7903
Number of pages	13
Journal	Journal of the European Ceramic Society
Volume	44
Issue number	13
DOIs	https://doi.org/10.1016/j.jeurceramsoc.2024.05.043
State	Published - Oct 2024

Keywords

CMAS corrosion
Crystallization
Glass-ceramics
Yb-Al-Si-O

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10.1016/j.jeurceramsoc.2024.05.043

Cite this

@article{aa2b3dbef62144b49bc6b1970f728d18,

title = "Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C",

abstract = "The intrinsic characteristics of Yb2O3-Al2O3-SiO2 (YbAS) glass-ceramics and their resistance to corrosion by molten calcium magnesium aluminosilicate (CMAS) at 1350 °C were systematically investigated. YbAS glass-ceramics, characterized by diverse compositions, maintaining phase stability over extended durations at elevated temperatures. After CMAS corrosion for 50 h, the main reaction phases were CaAl2Si2O8 and Ca2Yb8(SiO4)6O2, accompanied by multiple ion solid solution garnet in certain components. The glass component positioned along the eutectic line of Yb2Si2O7 and mullite, with an OB value marginally exceeding that of CMAS, exhibits superior corrosion resistance to CMAS. This finding offers valuable insights for the subsequent design of environmental barrier coatings (EBCs).",

keywords = "CMAS corrosion, Crystallization, Glass-ceramics, Yb-Al-Si-O",

author = "Xinyu Meng and Yujie Ma and Chun Guo and Bo Chen and Shaobo Yang and Juanli Deng and Shangwu Fan",

note = "Publisher Copyright: {\textcopyright} 2024 Elsevier Ltd",

year = "2024",

month = oct,

doi = "10.1016/j.jeurceramsoc.2024.05.043",

language = "英语",

volume = "44",

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T1 - Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C

AU - Meng, Xinyu

AU - Ma, Yujie

AU - Guo, Chun

AU - Chen, Bo

AU - Yang, Shaobo

AU - Deng, Juanli

AU - Fan, Shangwu

PY - 2024/10

Y1 - 2024/10

N2 - The intrinsic characteristics of Yb2O3-Al2O3-SiO2 (YbAS) glass-ceramics and their resistance to corrosion by molten calcium magnesium aluminosilicate (CMAS) at 1350 °C were systematically investigated. YbAS glass-ceramics, characterized by diverse compositions, maintaining phase stability over extended durations at elevated temperatures. After CMAS corrosion for 50 h, the main reaction phases were CaAl2Si2O8 and Ca2Yb8(SiO4)6O2, accompanied by multiple ion solid solution garnet in certain components. The glass component positioned along the eutectic line of Yb2Si2O7 and mullite, with an OB value marginally exceeding that of CMAS, exhibits superior corrosion resistance to CMAS. This finding offers valuable insights for the subsequent design of environmental barrier coatings (EBCs).

AB - The intrinsic characteristics of Yb2O3-Al2O3-SiO2 (YbAS) glass-ceramics and their resistance to corrosion by molten calcium magnesium aluminosilicate (CMAS) at 1350 °C were systematically investigated. YbAS glass-ceramics, characterized by diverse compositions, maintaining phase stability over extended durations at elevated temperatures. After CMAS corrosion for 50 h, the main reaction phases were CaAl2Si2O8 and Ca2Yb8(SiO4)6O2, accompanied by multiple ion solid solution garnet in certain components. The glass component positioned along the eutectic line of Yb2Si2O7 and mullite, with an OB value marginally exceeding that of CMAS, exhibits superior corrosion resistance to CMAS. This finding offers valuable insights for the subsequent design of environmental barrier coatings (EBCs).

KW - CMAS corrosion

KW - Crystallization

KW - Glass-ceramics

KW - Yb-Al-Si-O

UR - https://www.scopus.com/pages/publications/85194379165

U2 - 10.1016/j.jeurceramsoc.2024.05.043

DO - 10.1016/j.jeurceramsoc.2024.05.043

M3 - 文章

AN - SCOPUS:85194379165

SN - 0955-2219

VL - 44

SP - 7891

EP - 7903

JO - Journal of the European Ceramic Society

JF - Journal of the European Ceramic Society

IS - 13

ER -

Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C

Abstract

Keywords

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Cite this

Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C

Abstract

Keywords

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Cite this

Corrosion resistance and microstructural evolution of Yb-Al-Si-O glass-ceramics under molten Ca-Mg-Al-Si environment at 1350 °C