Codependence between crystalline and photovoltage evolutions in P3HT:PCBM solar cells probed with in-operando GIWAXS

Daniel Moseguí González; Christoph J. Schaffer; Stephan Pröller; Johannes Schlipf; Lin Song; Sigrid Bernstorff; Eva M. Herzig; Peter Müller-Buschbaum

doi:10.1021/acsami.6b15661

Codependence between crystalline and photovoltage evolutions in P3HT:PCBM solar cells probed with in-operando GIWAXS

Daniel Moseguí González, Christoph J. Schaffer, Stephan Pröller, Johannes Schlipf, Lin Song, Sigrid Bernstorff, Eva M. Herzig, Peter Müller-Buschbaum

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

We address the correlation between the crystalline state of photoactive materials in a model organic solar cell based on poly(3-hexylthiophene-2,5-diyl):phenyl-C60-butyric acid methyl ester (P3HT:PCBM) and the photovoltage in an in-operando investigation. I-V curves are simultaneously measured together with grazing incidence wide-angle X-ray scattering probing the crystalline state of the device active layer as a function of the operation time. The results show a high degree of correlation between open-circuit voltage VOC and the crystalline state of P3HT.

Original language	English
Pages (from-to)	3282-3287
Number of pages	6
Journal	ACS Applied Materials and Interfaces
Volume	9
Issue number	4
DOIs	https://doi.org/10.1021/acsami.6b15661
State	Published - 1 Feb 2017
Externally published	Yes

Keywords

Crystallinity
GIWAXS
In-operando
Nanomorphology
Organic photovoltaics

Access to Document

10.1021/acsami.6b15661

Cite this

@article{0caeaba92b0b4425ac9ffd6813703507,

title = "Codependence between crystalline and photovoltage evolutions in P3HT:PCBM solar cells probed with in-operando GIWAXS",

abstract = "We address the correlation between the crystalline state of photoactive materials in a model organic solar cell based on poly(3-hexylthiophene-2,5-diyl):phenyl-C60-butyric acid methyl ester (P3HT:PCBM) and the photovoltage in an in-operando investigation. I-V curves are simultaneously measured together with grazing incidence wide-angle X-ray scattering probing the crystalline state of the device active layer as a function of the operation time. The results show a high degree of correlation between open-circuit voltage VOC and the crystalline state of P3HT.",

keywords = "Crystallinity, GIWAXS, In-operando, Nanomorphology, Organic photovoltaics",

author = "Gonz{\'a}lez, {Daniel Mosegu{\'i}} and Schaffer, {Christoph J.} and Stephan Pr{\"o}ller and Johannes Schlipf and Lin Song and Sigrid Bernstorff and Herzig, {Eva M.} and Peter M{\"u}ller-Buschbaum",

year = "2017",

month = feb,

day = "1",

doi = "10.1021/acsami.6b15661",

language = "英语",

volume = "9",

pages = "3282--3287",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - Codependence between crystalline and photovoltage evolutions in P3HT:PCBM solar cells probed with in-operando GIWAXS

AU - González, Daniel Moseguí

AU - Schaffer, Christoph J.

AU - Pröller, Stephan

AU - Schlipf, Johannes

AU - Song, Lin

AU - Bernstorff, Sigrid

AU - Herzig, Eva M.

AU - Müller-Buschbaum, Peter

PY - 2017/2/1

Y1 - 2017/2/1

N2 - We address the correlation between the crystalline state of photoactive materials in a model organic solar cell based on poly(3-hexylthiophene-2,5-diyl):phenyl-C60-butyric acid methyl ester (P3HT:PCBM) and the photovoltage in an in-operando investigation. I-V curves are simultaneously measured together with grazing incidence wide-angle X-ray scattering probing the crystalline state of the device active layer as a function of the operation time. The results show a high degree of correlation between open-circuit voltage VOC and the crystalline state of P3HT.

AB - We address the correlation between the crystalline state of photoactive materials in a model organic solar cell based on poly(3-hexylthiophene-2,5-diyl):phenyl-C60-butyric acid methyl ester (P3HT:PCBM) and the photovoltage in an in-operando investigation. I-V curves are simultaneously measured together with grazing incidence wide-angle X-ray scattering probing the crystalline state of the device active layer as a function of the operation time. The results show a high degree of correlation between open-circuit voltage VOC and the crystalline state of P3HT.

KW - Crystallinity

KW - GIWAXS

KW - In-operando

KW - Nanomorphology

KW - Organic photovoltaics

UR - http://www.scopus.com/inward/record.url?scp=85011710567&partnerID=8YFLogxK

U2 - 10.1021/acsami.6b15661

DO - 10.1021/acsami.6b15661

M3 - 文章

C2 - 28094911

AN - SCOPUS:85011710567

SN - 1944-8244

VL - 9

SP - 3282

EP - 3287

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 4

ER -

Codependence between crystalline and photovoltage evolutions in P3HT:PCBM solar cells probed with in-operando GIWAXS

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this