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Chiral assembly of dodecahedral cavities into porous metal–organic frameworks

  • Hui Yang
  • , Fei Wang
  • , Yao Kang
  • , Tie Hu Li
  • , Jian Zhang
  • CAS - Fujian Institute of Research on the Structure of Matter
  • Northwestern Polytechnical University Xian

Research output: Contribution to journalArticlepeer-review

45 Scopus citations

Abstract

Corner-sharing assembly of dodecahedral cavities with both paddle-wheel [M2(CO2)4] units and trimeric [M33-OH)(CO2)6] units leads to two isomorphous chiral microporous metal–organic frameworks, where the heterometallic framework has high surface area and excellent CO2/N2 adsorption selectivity.

Original languageEnglish
Pages (from-to)9424-9426
Number of pages3
JournalChemical Communications
Volume48
Issue number75
DOIs
StatePublished - 22 Aug 2012

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