BF3·Et2O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

Zheng Dong Liu; Yong Zheng Chang; Chang Jin Ou; Jin Yi Lin; Ling Hai Xie; Cheng Rong Yin; Ming Deng Yi; Yan Qian; Nai En Shi; Wei Huang

doi:10.1039/c1py00203a

BF₃·Et₂O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

Zheng Dong Liu
, Yong Zheng Chang
, Chang Jin Ou
, Jin Yi Lin
, Ling Hai Xie
, Cheng Rong Yin
, Ming Deng Yi
, Yan Qian
, Nai En Shi
, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF₃·Et₂O-mediated Friedel-Crafts polymerization of AB, AB₂ and AB₄-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.

Original language	English
Pages (from-to)	2179-2182
Number of pages	4
Journal	Polymer Chemistry
Volume	2
Issue number	10
DOIs	https://doi.org/10.1039/c1py00203a
State	Published - Oct 2011
Externally published	Yes

Access to Document

10.1039/c1py00203a

Cite this

@article{3b98599f578844358ea57714499acacd,

title = "BF3·Et2O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors",

abstract = "C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel-Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.",

author = "Liu, \{Zheng Dong\} and Chang, \{Yong Zheng\} and Ou, \{Chang Jin\} and Lin, \{Jin Yi\} and Xie, \{Ling Hai\} and Yin, \{Cheng Rong\} and Yi, \{Ming Deng\} and Yan Qian and Shi, \{Nai En\} and Wei Huang",

year = "2011",

month = oct,

doi = "10.1039/c1py00203a",

language = "英语",

volume = "2",

pages = "2179--2182",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - BF3·Et2O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

AU - Liu, Zheng Dong

AU - Chang, Yong Zheng

AU - Ou, Chang Jin

AU - Lin, Jin Yi

AU - Xie, Ling Hai

AU - Yin, Cheng Rong

AU - Yi, Ming Deng

AU - Qian, Yan

AU - Shi, Nai En

AU - Huang, Wei

PY - 2011/10

Y1 - 2011/10

N2 - C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel-Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.

AB - C-H bond functionalization offers a chance to develop a new concept of polymerization. In this article, a family of diarylfluorene-based π-conjugation-interrupted polymers (CIPs) with nonlinear or hyperbranched frameworks have been explored by BF3·Et2O-mediated Friedel-Crafts polymerization of AB, AB2 and AB4-type tertiary alcohol monomers at room temperature. Their chemical structures and optoelectronic properties have been characterized and the existence of strong intermolecular π-stacked aggregates have been observed. CIP semiconductors afford a new platform to explore novel functionality of organic devices in organic electronics or spinelectronics.

UR - https://www.scopus.com/pages/publications/80052696174

U2 - 10.1039/c1py00203a

DO - 10.1039/c1py00203a

M3 - 文章

AN - SCOPUS:80052696174

SN - 1759-9954

VL - 2

SP - 2179

EP - 2182

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 10

ER -

BF₃·Et₂O-mediated Friedel-Crafts C-H bond polymerization to synthesize π-conjugation-interrupted polymer semiconductors

Abstract

Access to Document

Other files and links

Fingerprint

Cite this