Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

Biao Zhang; Xibo Yan; Pierre Alcouffe; Aurelia Charlot; Etienne Fleury; Julien Bernard

doi:10.1021/acsmacrolett.5b00534

Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

Biao Zhang
, Xibo Yan
, Pierre Alcouffe
, Aurelia Charlot
, Etienne Fleury
, Julien Bernard

Université de Lyon
Institut national des sciences appliquées Lyon
CNRS

Research output: Contribution to journal › Letter › peer-review

61 Scopus citations

Abstract

The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (Đ typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.

Original language	English
Pages (from-to)	1008-1011
Number of pages	4
Journal	ACS Macro Letters
Volume	4
Issue number	9
DOIs	https://doi.org/10.1021/acsmacrolett.5b00534
State	Published - 15 Sep 2015
Externally published	Yes

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10.1021/acsmacrolett.5b00534

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title = "Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly",

abstract = "The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s ({\D} typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.",

author = "Biao Zhang and Xibo Yan and Pierre Alcouffe and Aurelia Charlot and Etienne Fleury and Julien Bernard",

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year = "2015",

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doi = "10.1021/acsmacrolett.5b00534",

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T1 - Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers

T2 - En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

AU - Zhang, Biao

AU - Yan, Xibo

AU - Alcouffe, Pierre

AU - Charlot, Aurelia

AU - Fleury, Etienne

AU - Bernard, Julien

PY - 2015/9/15

Y1 - 2015/9/15

N2 - The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (Đ typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.

AB - The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (Đ typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.

UR - https://www.scopus.com/pages/publications/84941646784

U2 - 10.1021/acsmacrolett.5b00534

DO - 10.1021/acsmacrolett.5b00534

M3 - 快报

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VL - 4

SP - 1008

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JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 9

ER -

Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

Abstract

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