Applying low-salinity water to alter wettability in carbonate oil reservoirs: an experimental study

Seawater has been widely used as an injection fluid for maintaining pressure in sandstone and carbonate reservoirs. In the literature related to EOR research, it was noted that diluted seawater (low-salinity water) can highly improve recovery due to the specific ions (such as Ca²⁺, Mg²⁺, and SO₄²⁻). Such conclusions lead to the application of “Smart Water” in which changing the ion composition of injected water alters wettability and enhances recovery. Although many theories have been established to explain the mechanism of this phenomenon, almost all of them are limited to sandstone rocks, and the impact of smart water on carbonated reservoirs has rarely been explored. This study experimentally investigates the impact of the injection of high- and low-salinity and smart water on the change of wettability and recovery improvement in an Iranian South oil reservoir. Two different sets of experimental work were conducted. In the first set of experiments, the effect of formation water, diluted formation water (from 223,969 to 5000 ppm and 2000 ppm), seawater (initially 51,400 ppm), and diluted seawater on wettability alteration is investigated by monitoring the contact angle and relative permeability variation. The results showed that dilution of seawater to 2000 ppm has the most impact on wettability alteration. The relative permeability changed, and the contact angle decreased by a significant value of 100°, and recovery increased by about 71%. In the second set, the effect of ion change on the result was studied. For this purpose, the sulfate ion of diluted seawater (2000 ppm) is substituted by phosphate ion (H₂PO₄⁻). The results show the wettability alteration similar to the sulfate one. This study sheds light on the possible mechanism of wettability alteration in the carbonate reservoir, and the result will help to design a better low-salinity injection scenario.