Antimony(V) chloride-benzyltriethylammonium chloride complex as an efficient catalyst for friedel-crafts acylation reactions

An Ping Huang; Xue Yuan Liu; Lian Hua Li; Xiao Li Wu; Wei Min Liu; Yong Min Liang

doi:10.1002/adsc.200303233

Antimony(V) chloride-benzyltriethylammonium chloride complex as an efficient catalyst for friedel-crafts acylation reactions

An Ping Huang
, Xue Yuan Liu
, Lian Hua Li
, Xiao Li Wu
, Wei Min Liu
, Yong Min Liang

Lanzhou University
CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A novel catalytic system, the complex of antimony(V) chloride (SbCl ₅) and benzyltriethylammonium chloride (TEBA), C₆H ₅CH₂NEt₃(SbCl₅)₂Cl complex, is described for Friedel-Crafts acylation reactions of aromatics with acyl and sulfonyl chlorides. The catalyst has a number of useful characteristics, such as ready access, minimal toxicity, reusability, insensitivity to atmosphere and moisture, rapid acylation with high yield, and ease of operation.

Original language	English
Pages (from-to)	599-602
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	346
Issue number	6
DOIs	https://doi.org/10.1002/adsc.200303233
State	Published - Jun 2004
Externally published	Yes

Keywords

Antimony(V) chloride
Benzyltriethylammonium chloride
Catalysis
Friedel-Crafts acylation reactions
Lewis acids

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10.1002/adsc.200303233

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title = "Antimony(V) chloride-benzyltriethylammonium chloride complex as an efficient catalyst for friedel-crafts acylation reactions",

abstract = "A novel catalytic system, the complex of antimony(V) chloride (SbCl 5) and benzyltriethylammonium chloride (TEBA), C6H 5CH2NEt3(SbCl5)2Cl complex, is described for Friedel-Crafts acylation reactions of aromatics with acyl and sulfonyl chlorides. The catalyst has a number of useful characteristics, such as ready access, minimal toxicity, reusability, insensitivity to atmosphere and moisture, rapid acylation with high yield, and ease of operation.",

keywords = "Antimony(V) chloride, Benzyltriethylammonium chloride, Catalysis, Friedel-Crafts acylation reactions, Lewis acids",

author = "Huang, \{An Ping\} and Liu, \{Xue Yuan\} and Li, \{Lian Hua\} and Wu, \{Xiao Li\} and Liu, \{Wei Min\} and Liang, \{Yong Min\}",

year = "2004",

month = jun,

doi = "10.1002/adsc.200303233",

language = "英语",

volume = "346",

pages = "599--602",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

publisher = "Wiley-VCH Verlag",

number = "6",

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TY - JOUR

T1 - Antimony(V) chloride-benzyltriethylammonium chloride complex as an efficient catalyst for friedel-crafts acylation reactions

AU - Huang, An Ping

AU - Liu, Xue Yuan

AU - Li, Lian Hua

AU - Wu, Xiao Li

AU - Liu, Wei Min

AU - Liang, Yong Min

PY - 2004/6

Y1 - 2004/6

N2 - A novel catalytic system, the complex of antimony(V) chloride (SbCl 5) and benzyltriethylammonium chloride (TEBA), C6H 5CH2NEt3(SbCl5)2Cl complex, is described for Friedel-Crafts acylation reactions of aromatics with acyl and sulfonyl chlorides. The catalyst has a number of useful characteristics, such as ready access, minimal toxicity, reusability, insensitivity to atmosphere and moisture, rapid acylation with high yield, and ease of operation.

AB - A novel catalytic system, the complex of antimony(V) chloride (SbCl 5) and benzyltriethylammonium chloride (TEBA), C6H 5CH2NEt3(SbCl5)2Cl complex, is described for Friedel-Crafts acylation reactions of aromatics with acyl and sulfonyl chlorides. The catalyst has a number of useful characteristics, such as ready access, minimal toxicity, reusability, insensitivity to atmosphere and moisture, rapid acylation with high yield, and ease of operation.

KW - Antimony(V) chloride

KW - Benzyltriethylammonium chloride

KW - Catalysis

KW - Friedel-Crafts acylation reactions

KW - Lewis acids

UR - https://www.scopus.com/pages/publications/3042746903

U2 - 10.1002/adsc.200303233

DO - 10.1002/adsc.200303233

M3 - 文章

AN - SCOPUS:3042746903

SN - 1615-4150

VL - 346

SP - 599

EP - 602

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 6

ER -

Antimony(V) chloride-benzyltriethylammonium chloride complex as an efficient catalyst for friedel-crafts acylation reactions

Abstract

Keywords

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