An unusual (3,4)-connected cubic-C3N4 type network constructed with [FeIII(Tp)(CN)3]- (Tp - = hydrotris(pyrazolyl)borate)

Yong Hua Li; Yong Gang Min; Shi Wang; Jing Lin Zuo; Lian Hui Wang; Wei Huang

doi:10.1039/c3ce27001g

An unusual (3,4)-connected cubic-C₃N₄ type network constructed with [Fe^III(Tp)(CN)₃]^- (Tp ^- = hydrotris(pyrazolyl)borate)

Yong Hua Li
, Yong Gang Min
, Shi Wang
, Jing Lin Zuo
, Lian Hui Wang
, Wei Huang

Nanjing University of Posts and Telecommunications
Nanjing University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

By using a pre-designed anionic precursor [Fe^III(Tp)(CN) ₃]^- (Tp^- = hydrotris(pyrazolyl)borate) as a structural building unit, a novel cyanide-bridged metal-organic framework (MOF), [(Tp)₆Fe^II₄Fe^III ₂(CN)₁₈Zn₅(H₂O) _3.25·(CH₃CN)_4.75(C₄H ₁₀O)_2.125(H₂O)₂]_n (1), has been synthesized and characterized by single crystal X-ray diffraction. There are two kinds of secondary building units (SBUs), cube and trigonal bipyramid (TBP) in complex 1. The cubic SBU contains a Zn₄Fe ₄(CN)₁₂ core. Each cube connects to four TBPs and each TBP binds three cubes through its equatorial bonds giving rise to an unprecedented cyanide-bridged (3,4)-connected cubic-C₃N₄ type network.

Original language	English
Pages (from-to)	3772-3775
Number of pages	4
Journal	CrystEngComm
Volume	15
Issue number	19
DOIs	https://doi.org/10.1039/c3ce27001g
State	Published - 21 May 2013
Externally published	Yes

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title = "An unusual (3,4)-connected cubic-C3N4 type network constructed with [FeIII(Tp)(CN)3]- (Tp - = hydrotris(pyrazolyl)borate)",

abstract = "By using a pre-designed anionic precursor [FeIII(Tp)(CN) 3]- (Tp- = hydrotris(pyrazolyl)borate) as a structural building unit, a novel cyanide-bridged metal-organic framework (MOF), [(Tp)6FeII4FeIII 2(CN)18Zn5(H2O) 3.25·(CH3CN)4.75(C4H 10O)2.125(H2O)2]n (1), has been synthesized and characterized by single crystal X-ray diffraction. There are two kinds of secondary building units (SBUs), cube and trigonal bipyramid (TBP) in complex 1. The cubic SBU contains a Zn4Fe 4(CN)12 core. Each cube connects to four TBPs and each TBP binds three cubes through its equatorial bonds giving rise to an unprecedented cyanide-bridged (3,4)-connected cubic-C3N4 type network.",

author = "Li, \{Yong Hua\} and Min, \{Yong Gang\} and Shi Wang and Zuo, \{Jing Lin\} and Wang, \{Lian Hui\} and Wei Huang",

year = "2013",

month = may,

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doi = "10.1039/c3ce27001g",

language = "英语",

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T1 - An unusual (3,4)-connected cubic-C3N4 type network constructed with [FeIII(Tp)(CN)3]- (Tp - = hydrotris(pyrazolyl)borate)

AU - Li, Yong Hua

AU - Min, Yong Gang

AU - Wang, Shi

AU - Zuo, Jing Lin

AU - Wang, Lian Hui

AU - Huang, Wei

PY - 2013/5/21

Y1 - 2013/5/21

N2 - By using a pre-designed anionic precursor [FeIII(Tp)(CN) 3]- (Tp- = hydrotris(pyrazolyl)borate) as a structural building unit, a novel cyanide-bridged metal-organic framework (MOF), [(Tp)6FeII4FeIII 2(CN)18Zn5(H2O) 3.25·(CH3CN)4.75(C4H 10O)2.125(H2O)2]n (1), has been synthesized and characterized by single crystal X-ray diffraction. There are two kinds of secondary building units (SBUs), cube and trigonal bipyramid (TBP) in complex 1. The cubic SBU contains a Zn4Fe 4(CN)12 core. Each cube connects to four TBPs and each TBP binds three cubes through its equatorial bonds giving rise to an unprecedented cyanide-bridged (3,4)-connected cubic-C3N4 type network.

AB - By using a pre-designed anionic precursor [FeIII(Tp)(CN) 3]- (Tp- = hydrotris(pyrazolyl)borate) as a structural building unit, a novel cyanide-bridged metal-organic framework (MOF), [(Tp)6FeII4FeIII 2(CN)18Zn5(H2O) 3.25·(CH3CN)4.75(C4H 10O)2.125(H2O)2]n (1), has been synthesized and characterized by single crystal X-ray diffraction. There are two kinds of secondary building units (SBUs), cube and trigonal bipyramid (TBP) in complex 1. The cubic SBU contains a Zn4Fe 4(CN)12 core. Each cube connects to four TBPs and each TBP binds three cubes through its equatorial bonds giving rise to an unprecedented cyanide-bridged (3,4)-connected cubic-C3N4 type network.

UR - https://www.scopus.com/pages/publications/84876715064

U2 - 10.1039/c3ce27001g

DO - 10.1039/c3ce27001g

M3 - 文章

AN - SCOPUS:84876715064

SN - 1466-8033

VL - 15

SP - 3772

EP - 3775

JO - CrystEngComm

JF - CrystEngComm

IS - 19

ER -

An unusual (3,4)-connected cubic-C₃N₄ type network constructed with [Fe^III(Tp)(CN)₃]^- (Tp ^- = hydrotris(pyrazolyl)borate)

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