An azido ester plasticizer, 1,3-Di(azidoacetoxy)-2,2-Di(azidomethyl) propane (PEAA): Synthesis, characterization and thermal properties

Shaojun Qoi; Huiqing Fan; Chao Gao; Xiaodong Zheng; Xiaoxian Gan

doi:10.1002/prep.200600028

An azido ester plasticizer, 1,3-Di(azidoacetoxy)-2,2-Di(azidomethyl) propane (PEAA): Synthesis, characterization and thermal properties

Shaojun Qoi
, Huiqing Fan
, Chao Gao
, Xiaodong Zheng
, Xiaoxian Gan

School of Materials Sience and Engineering

Northwestern Polytechnical University Xian
Xi'an Modern Chemistry Research Institute

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A polyazido compound, 1,3-di(azidoacetoxy)-2,2-di(azidomethyl)propane (PEAA) was synthesized and identified. Thermal properties of PEAA, such as the glass transition temperature (T_g), differential scanning calorimetry (DSC) and thermogravimetric analysis (DTG) were investigated in detail. Two steps in the course of thermal decomposition of PEAA were observed clearly, and some gases, carbon monoxide, carbon dioxide, nitrogen, hydrocyanic acid, methane and 2-methyl-1,3-butadiene were identified as decomposition products by in situ cell FTIR. The pyrolysis mechanism was also proposed.

Original language	English
Pages (from-to)	205-208
Number of pages	4
Journal	Propellants, Explosives, Pyrotechnics
Volume	31
Issue number	3
DOIs	https://doi.org/10.1002/prep.200600028
State	Published - Jun 2006

Keywords

Azido Ester Plasticizer
Synthesis
Thermal Properties

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10.1002/prep.200600028

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title = "An azido ester plasticizer, 1,3-Di(azidoacetoxy)-2,2-Di(azidomethyl) propane (PEAA): Synthesis, characterization and thermal properties",

abstract = "A polyazido compound, 1,3-di(azidoacetoxy)-2,2-di(azidomethyl)propane (PEAA) was synthesized and identified. Thermal properties of PEAA, such as the glass transition temperature (Tg), differential scanning calorimetry (DSC) and thermogravimetric analysis (DTG) were investigated in detail. Two steps in the course of thermal decomposition of PEAA were observed clearly, and some gases, carbon monoxide, carbon dioxide, nitrogen, hydrocyanic acid, methane and 2-methyl-1,3-butadiene were identified as decomposition products by in situ cell FTIR. The pyrolysis mechanism was also proposed.",

keywords = "Azido Ester Plasticizer, Synthesis, Thermal Properties",

author = "Shaojun Qoi and Huiqing Fan and Chao Gao and Xiaodong Zheng and Xiaoxian Gan",

year = "2006",

month = jun,

doi = "10.1002/prep.200600028",

language = "英语",

volume = "31",

pages = "205--208",

journal = "Propellants, Explosives, Pyrotechnics",

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TY - JOUR

T1 - An azido ester plasticizer, 1,3-Di(azidoacetoxy)-2,2-Di(azidomethyl) propane (PEAA)

T2 - Synthesis, characterization and thermal properties

AU - Qoi, Shaojun

AU - Fan, Huiqing

AU - Gao, Chao

AU - Zheng, Xiaodong

AU - Gan, Xiaoxian

PY - 2006/6

Y1 - 2006/6

N2 - A polyazido compound, 1,3-di(azidoacetoxy)-2,2-di(azidomethyl)propane (PEAA) was synthesized and identified. Thermal properties of PEAA, such as the glass transition temperature (Tg), differential scanning calorimetry (DSC) and thermogravimetric analysis (DTG) were investigated in detail. Two steps in the course of thermal decomposition of PEAA were observed clearly, and some gases, carbon monoxide, carbon dioxide, nitrogen, hydrocyanic acid, methane and 2-methyl-1,3-butadiene were identified as decomposition products by in situ cell FTIR. The pyrolysis mechanism was also proposed.

AB - A polyazido compound, 1,3-di(azidoacetoxy)-2,2-di(azidomethyl)propane (PEAA) was synthesized and identified. Thermal properties of PEAA, such as the glass transition temperature (Tg), differential scanning calorimetry (DSC) and thermogravimetric analysis (DTG) were investigated in detail. Two steps in the course of thermal decomposition of PEAA were observed clearly, and some gases, carbon monoxide, carbon dioxide, nitrogen, hydrocyanic acid, methane and 2-methyl-1,3-butadiene were identified as decomposition products by in situ cell FTIR. The pyrolysis mechanism was also proposed.

KW - Azido Ester Plasticizer

KW - Synthesis

KW - Thermal Properties

UR - https://www.scopus.com/pages/publications/33745803188

U2 - 10.1002/prep.200600028

DO - 10.1002/prep.200600028

M3 - 文章

AN - SCOPUS:33745803188

SN - 0721-3115

VL - 31

SP - 205

EP - 208

JO - Propellants, Explosives, Pyrotechnics

JF - Propellants, Explosives, Pyrotechnics

IS - 3

ER -

An azido ester plasticizer, 1,3-Di(azidoacetoxy)-2,2-Di(azidomethyl) propane (PEAA): Synthesis, characterization and thermal properties

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Keywords

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