Ablation behavior of ZrC-SiHfOC-MoSi2 coating for carbon/carbon composites under Ar-O2 plasma flame

Xuemeng Zhang; Yuyu Zhang; Kaifei Fan; Ralf Riedel; Hongbin Li; Jia Sun; Hejun Li

doi:10.1016/j.corsci.2024.111944

Ablation behavior of ZrC-SiHfOC-MoSi₂ coating for carbon/carbon composites under Ar-O₂ plasma flame

Xuemeng Zhang
, Yuyu Zhang
, Kaifei Fan
, Ralf Riedel
, Hongbin Li
, Jia Sun
, Hejun Li

School of Materials Sience and Engineering

Northwestern Polytechnical University Xian
Technische Universität Darmstadt
China Aerodynamics Research and Development Center

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi₂ coating was investigated. The results showed that the MoSi₂ shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large-area peeling after an Ar-O₂ plasma flame ablation for 90 s. In contrast, ZrC-SiHfOC-MoSi₂ coating revealed low ablation rates after ablation for 360 s, with the mass and linear ablation rates of −0.05 mg/s and 0.14 μm/s, respectively. MoSi₂ provides rich SiO₂ to form ZrSiO₄ to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.

Original language	English
Article number	111944
Journal	Corrosion Science
Volume	231
DOIs	https://doi.org/10.1016/j.corsci.2024.111944
State	Published - 1 May 2024

Keywords

C/C Composites
Core-Shell Powders
Plasma Spraying
Polymer-Derived Ceramics (PDCs)
ZrC

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10.1016/j.corsci.2024.111944

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@article{6545c6897a7d4c5596b07d3b761629c7,

title = "Ablation behavior of ZrC-SiHfOC-MoSi2 coating for carbon/carbon composites under Ar-O2 plasma flame",

abstract = "To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi2 coating was investigated. The results showed that the MoSi2 shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large-area peeling after an Ar-O2 plasma flame ablation for 90 s. In contrast, ZrC-SiHfOC-MoSi2 coating revealed low ablation rates after ablation for 360 s, with the mass and linear ablation rates of −0.05 mg/s and 0.14 μm/s, respectively. MoSi2 provides rich SiO2 to form ZrSiO4 to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.",

keywords = "C/C Composites, Core-Shell Powders, Plasma Spraying, Polymer-Derived Ceramics (PDCs), ZrC",

author = "Xuemeng Zhang and Yuyu Zhang and Kaifei Fan and Ralf Riedel and Hongbin Li and Jia Sun and Hejun Li",

note = "Publisher Copyright: {\textcopyright} 2024 Elsevier Ltd",

year = "2024",

month = may,

day = "1",

doi = "10.1016/j.corsci.2024.111944",

language = "英语",

volume = "231",

journal = "Corrosion Science",

issn = "0010-938X",

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TY - JOUR

T1 - Ablation behavior of ZrC-SiHfOC-MoSi2 coating for carbon/carbon composites under Ar-O2 plasma flame

AU - Zhang, Xuemeng

AU - Zhang, Yuyu

AU - Fan, Kaifei

AU - Riedel, Ralf

AU - Li, Hongbin

AU - Sun, Jia

AU - Li, Hejun

PY - 2024/5/1

Y1 - 2024/5/1

N2 - To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi2 coating was investigated. The results showed that the MoSi2 shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large-area peeling after an Ar-O2 plasma flame ablation for 90 s. In contrast, ZrC-SiHfOC-MoSi2 coating revealed low ablation rates after ablation for 360 s, with the mass and linear ablation rates of −0.05 mg/s and 0.14 μm/s, respectively. MoSi2 provides rich SiO2 to form ZrSiO4 to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.

AB - To improve ablation resistance of ZrC-SiMOC-based (M = transition metal) coatings, a ZrC-SiHfOC-MoSi2 coating was investigated. The results showed that the MoSi2 shell limits the decomposition of SiC under SAPS and decreases pores of the coating. ZrC-SiHfOC coating showed large-area peeling after an Ar-O2 plasma flame ablation for 90 s. In contrast, ZrC-SiHfOC-MoSi2 coating revealed low ablation rates after ablation for 360 s, with the mass and linear ablation rates of −0.05 mg/s and 0.14 μm/s, respectively. MoSi2 provides rich SiO2 to form ZrSiO4 to reduce the damage by plasma flame, thereby improving the ablation resistance of ZrC-based coatings.

KW - C/C Composites

KW - Core-Shell Powders

KW - Plasma Spraying

KW - Polymer-Derived Ceramics (PDCs)

KW - ZrC

UR - https://www.scopus.com/pages/publications/85187204348

U2 - 10.1016/j.corsci.2024.111944

DO - 10.1016/j.corsci.2024.111944

M3 - 文章

AN - SCOPUS:85187204348

SN - 0010-938X

VL - 231

JO - Corrosion Science

JF - Corrosion Science

M1 - 111944

ER -

Ablation behavior of ZrC-SiHfOC-MoSi₂ coating for carbon/carbon composites under Ar-O₂ plasma flame

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Keywords

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