A Synthetic Strategy for the Preparation of Fused [5,6,5,5]-Tetracyclic Energetic Compounds

Caijin Lei; Jie Tang; Qinghua Zhang; Hongwei Yang; Guangbin Cheng

doi:10.1021/acs.orglett.3c00630

A Synthetic Strategy for the Preparation of Fused [5,6,5,5]-Tetracyclic Energetic Compounds

Caijin Lei
, Jie Tang
, Qinghua Zhang
, Hongwei Yang
, Guangbin Cheng

School of Astronautics

Nanjing University of Science and Technology

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

This study explores a straightforward synthetic strategy for preparing fused [5,6,5,5]-tetracyclic energetic compounds. Compound 4 has a high thermostability (T_d = 307 °C), which is comparable to that of traditional heat-resistant explosive HNS (T_d = 318 °C), but a higher detonation velocity (8262 m s^-1) than HNS (7612 m s^-1). These results indicate that compound 4 deserves further investigation as a potential heat-resistant explosive.

Original language	English
Pages (from-to)	2461-2465
Number of pages	5
Journal	Organic Letters
Volume	25
Issue number	14
DOIs	https://doi.org/10.1021/acs.orglett.3c00630
State	Published - 14 Apr 2023

Access to Document

10.1021/acs.orglett.3c00630

Cite this

@article{3e137fecd2214b53b714e408ebe1bbb8,

title = "A Synthetic Strategy for the Preparation of Fused [5,6,5,5]-Tetracyclic Energetic Compounds",

abstract = "This study explores a straightforward synthetic strategy for preparing fused [5,6,5,5]-tetracyclic energetic compounds. Compound 4 has a high thermostability (Td = 307 °C), which is comparable to that of traditional heat-resistant explosive HNS (Td = 318 °C), but a higher detonation velocity (8262 m s-1) than HNS (7612 m s-1). These results indicate that compound 4 deserves further investigation as a potential heat-resistant explosive.",

author = "Caijin Lei and Jie Tang and Qinghua Zhang and Hongwei Yang and Guangbin Cheng",

note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

year = "2023",

month = apr,

day = "14",

doi = "10.1021/acs.orglett.3c00630",

language = "英语",

volume = "25",

pages = "2461--2465",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "14",

}

TY - JOUR

T1 - A Synthetic Strategy for the Preparation of Fused [5,6,5,5]-Tetracyclic Energetic Compounds

AU - Lei, Caijin

AU - Tang, Jie

AU - Zhang, Qinghua

AU - Yang, Hongwei

AU - Cheng, Guangbin

PY - 2023/4/14

Y1 - 2023/4/14

N2 - This study explores a straightforward synthetic strategy for preparing fused [5,6,5,5]-tetracyclic energetic compounds. Compound 4 has a high thermostability (Td = 307 °C), which is comparable to that of traditional heat-resistant explosive HNS (Td = 318 °C), but a higher detonation velocity (8262 m s-1) than HNS (7612 m s-1). These results indicate that compound 4 deserves further investigation as a potential heat-resistant explosive.

AB - This study explores a straightforward synthetic strategy for preparing fused [5,6,5,5]-tetracyclic energetic compounds. Compound 4 has a high thermostability (Td = 307 °C), which is comparable to that of traditional heat-resistant explosive HNS (Td = 318 °C), but a higher detonation velocity (8262 m s-1) than HNS (7612 m s-1). These results indicate that compound 4 deserves further investigation as a potential heat-resistant explosive.

UR - https://www.scopus.com/pages/publications/85151908125

U2 - 10.1021/acs.orglett.3c00630

DO - 10.1021/acs.orglett.3c00630

M3 - 文章

C2 - 37010150

AN - SCOPUS:85151908125

SN - 1523-7060

VL - 25

SP - 2461

EP - 2465

JO - Organic Letters

JF - Organic Letters

IS - 14

ER -

A Synthetic Strategy for the Preparation of Fused [5,6,5,5]-Tetracyclic Energetic Compounds

Abstract

Access to Document

Other files and links

Fingerprint

Cite this