A rare cationic building block that generates a new type of polyhedral network with "cross-linked" pto topology

Matteo Lusi; Pierre B.A. Fechine; Kai Jie Chen; John J. Perry; Michael J. Zaworotko

doi:10.1039/c5cc10203k

A rare cationic building block that generates a new type of polyhedral network with "cross-linked" pto topology

Matteo Lusi
, Pierre B.A. Fechine
, Kai Jie Chen
, John J. Perry
, Michael J. Zaworotko

University of Limerick
Universidade Federal do Ceará

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A rare 8-connected cationic building block, [Cu₂L₈(μ-MF₆)]²⁺ (L = pyridyl ligand, M = Si, Ti, Ge, Zr or Sn), enables the formation of a small cubicuboctahedral supramolecular building block, SBB, when complexed by 2,4,6-tris(4-pyridyl)pyridine. The coordination network resulting from fusing the square faces of the SBBs can be described as a pto topology in which half of the square faces are cross-linked by MF₆^2- moieties, and represents the first example of a new 3,5-c topology.

Original language	English
Pages (from-to)	4160-4162
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	22
DOIs	https://doi.org/10.1039/c5cc10203k
State	Published - 2016
Externally published	Yes

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title = "A rare cationic building block that generates a new type of polyhedral network with {"}cross-linked{"} pto topology",

abstract = "A rare 8-connected cationic building block, [Cu2L8(μ-MF6)]2+ (L = pyridyl ligand, M = Si, Ti, Ge, Zr or Sn), enables the formation of a small cubicuboctahedral supramolecular building block, SBB, when complexed by 2,4,6-tris(4-pyridyl)pyridine. The coordination network resulting from fusing the square faces of the SBBs can be described as a pto topology in which half of the square faces are cross-linked by MF62- moieties, and represents the first example of a new 3,5-c topology.",

author = "Matteo Lusi and Fechine, \{Pierre B.A.\} and Chen, \{Kai Jie\} and Perry, \{John J.\} and Zaworotko, \{Michael J.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c5cc10203k",

language = "英语",

volume = "52",

pages = "4160--4162",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - A rare cationic building block that generates a new type of polyhedral network with "cross-linked" pto topology

AU - Lusi, Matteo

AU - Fechine, Pierre B.A.

AU - Chen, Kai Jie

AU - Perry, John J.

AU - Zaworotko, Michael J.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2016.

PY - 2016

Y1 - 2016

N2 - A rare 8-connected cationic building block, [Cu2L8(μ-MF6)]2+ (L = pyridyl ligand, M = Si, Ti, Ge, Zr or Sn), enables the formation of a small cubicuboctahedral supramolecular building block, SBB, when complexed by 2,4,6-tris(4-pyridyl)pyridine. The coordination network resulting from fusing the square faces of the SBBs can be described as a pto topology in which half of the square faces are cross-linked by MF62- moieties, and represents the first example of a new 3,5-c topology.

AB - A rare 8-connected cationic building block, [Cu2L8(μ-MF6)]2+ (L = pyridyl ligand, M = Si, Ti, Ge, Zr or Sn), enables the formation of a small cubicuboctahedral supramolecular building block, SBB, when complexed by 2,4,6-tris(4-pyridyl)pyridine. The coordination network resulting from fusing the square faces of the SBBs can be described as a pto topology in which half of the square faces are cross-linked by MF62- moieties, and represents the first example of a new 3,5-c topology.

UR - https://www.scopus.com/pages/publications/84960405712

U2 - 10.1039/c5cc10203k

DO - 10.1039/c5cc10203k

M3 - 文章

AN - SCOPUS:84960405712

SN - 1359-7345

VL - 52

SP - 4160

EP - 4162

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

A rare cationic building block that generates a new type of polyhedral network with "cross-linked" pto topology

Abstract

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