A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer

S. J. Chen; Q. Y. Zhang; J. W. Gu; M. L. Ma; L. Zhang; J. Zhou; Y. Y. Zhou

doi:10.3144/expresspolymlett.2012.48

A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer

S. J. Chen
, Q. Y. Zhang
, J. W. Gu
, M. L. Ma
, L. Zhang
, J. Zhou
, Y. Y. Zhou

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A new conjugated polymer with donor-accepter architectures poly[1,4-dioctyloxyphenylene-2,5-diylethenylene- (2,3-dipyridine-2-ylquinoxaline-5,8-diyl)ethylene] (PPV-BD) was synthesized successfully, in which the electron-donating unit was alkoxy substituted phenyl ring, and the electron-accepting unit was a quinoxaline. The resulting polymer had a lower band-gap (1.98 eV) compared to poly[2-methoxy-5-(2-ethyl)hexoxy-phenylenevinylene] (MEH-PPV, 2.12 eV), and was characterized by infrared spectroscopy (IR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), gel permeation chromatography (GPC), ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy and X-ray diffraction (XRD). Its photoinduced charge transfer applications in polymer solar cell (PSC) and trinitrotoluene (TNT) detection were studied respectively, and the results indicated that this polymer might be a good candidate material for PSC or detecting TNT in solution.

Original language	English
Pages (from-to)	454-464
Number of pages	11
Journal	Express Polymer Letters
Volume	6
Issue number	6
DOIs	https://doi.org/10.3144/expresspolymlett.2012.48
State	Published - Jun 2012

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Characterization
Chemosensor material
Photoinduced charge transfer
Photovoltaic material
Polymer synthesis

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Chen, S. J., Zhang, Q. Y., Gu, J. W., Ma, M. L., Zhang, L., Zhou, J., & Zhou, Y. Y. (2012). A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer. Express Polymer Letters, 6(6), 454-464. https://doi.org/10.3144/expresspolymlett.2012.48

@article{895927e196834ac1a026a3fd417d0a02,

title = "A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer",

abstract = "A new conjugated polymer with donor-accepter architectures poly[1,4-dioctyloxyphenylene-2,5-diylethenylene- (2,3-dipyridine-2-ylquinoxaline-5,8-diyl)ethylene] (PPV-BD) was synthesized successfully, in which the electron-donating unit was alkoxy substituted phenyl ring, and the electron-accepting unit was a quinoxaline. The resulting polymer had a lower band-gap (1.98 eV) compared to poly[2-methoxy-5-(2-ethyl)hexoxy-phenylenevinylene] (MEH-PPV, 2.12 eV), and was characterized by infrared spectroscopy (IR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), gel permeation chromatography (GPC), ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy and X-ray diffraction (XRD). Its photoinduced charge transfer applications in polymer solar cell (PSC) and trinitrotoluene (TNT) detection were studied respectively, and the results indicated that this polymer might be a good candidate material for PSC or detecting TNT in solution.",

keywords = "Characterization, Chemosensor material, Photoinduced charge transfer, Photovoltaic material, Polymer synthesis",

author = "Chen, \{S. J.\} and Zhang, \{Q. Y.\} and Gu, \{J. W.\} and Ma, \{M. L.\} and L. Zhang and J. Zhou and Zhou, \{Y. Y.\}",

year = "2012",

month = jun,

doi = "10.3144/expresspolymlett.2012.48",

language = "英语",

volume = "6",

pages = "454--464",

journal = "Express Polymer Letters",

issn = "1788-618X",

publisher = "BME-PT and GTE",

number = "6",

}

Chen, SJ, Zhang, QY , Gu, JW, Ma, ML, Zhang, L, Zhou, J & Zhou, YY 2012, 'A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer', Express Polymer Letters, vol. 6, no. 6, pp. 454-464. https://doi.org/10.3144/expresspolymlett.2012.48

A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer. / Chen, S. J.; Zhang, Q. Y.; Gu, J. W. et al.
In: Express Polymer Letters, Vol. 6, No. 6, 06.2012, p. 454-464.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline

T2 - Synthesis, characterization, and photoinduced charge transfer

AU - Chen, S. J.

AU - Zhang, Q. Y.

AU - Gu, J. W.

AU - Ma, M. L.

AU - Zhang, L.

AU - Zhou, J.

AU - Zhou, Y. Y.

PY - 2012/6

Y1 - 2012/6

N2 - A new conjugated polymer with donor-accepter architectures poly[1,4-dioctyloxyphenylene-2,5-diylethenylene- (2,3-dipyridine-2-ylquinoxaline-5,8-diyl)ethylene] (PPV-BD) was synthesized successfully, in which the electron-donating unit was alkoxy substituted phenyl ring, and the electron-accepting unit was a quinoxaline. The resulting polymer had a lower band-gap (1.98 eV) compared to poly[2-methoxy-5-(2-ethyl)hexoxy-phenylenevinylene] (MEH-PPV, 2.12 eV), and was characterized by infrared spectroscopy (IR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), gel permeation chromatography (GPC), ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy and X-ray diffraction (XRD). Its photoinduced charge transfer applications in polymer solar cell (PSC) and trinitrotoluene (TNT) detection were studied respectively, and the results indicated that this polymer might be a good candidate material for PSC or detecting TNT in solution.

AB - A new conjugated polymer with donor-accepter architectures poly[1,4-dioctyloxyphenylene-2,5-diylethenylene- (2,3-dipyridine-2-ylquinoxaline-5,8-diyl)ethylene] (PPV-BD) was synthesized successfully, in which the electron-donating unit was alkoxy substituted phenyl ring, and the electron-accepting unit was a quinoxaline. The resulting polymer had a lower band-gap (1.98 eV) compared to poly[2-methoxy-5-(2-ethyl)hexoxy-phenylenevinylene] (MEH-PPV, 2.12 eV), and was characterized by infrared spectroscopy (IR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), gel permeation chromatography (GPC), ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy and X-ray diffraction (XRD). Its photoinduced charge transfer applications in polymer solar cell (PSC) and trinitrotoluene (TNT) detection were studied respectively, and the results indicated that this polymer might be a good candidate material for PSC or detecting TNT in solution.

KW - Characterization

KW - Chemosensor material

KW - Photoinduced charge transfer

KW - Photovoltaic material

KW - Polymer synthesis

UR - https://www.scopus.com/pages/publications/84859198362

U2 - 10.3144/expresspolymlett.2012.48

DO - 10.3144/expresspolymlett.2012.48

M3 - 文章

AN - SCOPUS:84859198362

SN - 1788-618X

VL - 6

SP - 454

EP - 464

JO - Express Polymer Letters

JF - Express Polymer Letters

IS - 6

ER -

A new conjugated polymer with donor-acceptor architectures based on alternating 1,4-divinyl-2,5-dioctyloxybenzene and 5,8-(2,3-dipyridyl)-quinoxaline: Synthesis, characterization, and photoinduced charge transfer

Abstract

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Keywords

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