A lanthanide-transition metal coordination polymer: {[CuEu(Hbidc) 2(H2O)4].H2O}n (H 3bidc = 1hbenzimidazole- 5,6-dicarboxylic acid

Zhou Xin-Hui; Huang Wei

A lanthanide-transition metal coordination polymer: {[CuEu(Hbidc) ₂(H₂O)₄].H₂O}_n (H ₃bidc = 1hbenzimidazole- 5,6-dicarboxylic acid

Zhou Xin-Hui, Huang Wei

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title complex 1, {[CuEu(Hbidc)₂(H₂O) ₄].H₂O}_n (H₃bidc = 1H-benzimidazole- 5,6-dicarboxylic acid), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P¹, with a = 7.791(2), b = 12.058(3), c = 12.109(3) Å, α = 82.189(5), β = 72.407(5), γ = 89.184(4)̊, V = 1073.7(5) Å³, C₁₈H ₁₈CuEuN₄O₁₃, Mr = 713.86, Dc = 2.208 g/cm3, μ(MoKa) = 3.967 mm^-1, F(000) = 700, GOOF = 0.950, Z = 2, the final R = 0.0531 and wR = 0.1068 for I > 2σ(I). Complex 1 possess a tape-like chain structure consisting of Eu₂C₈O₄ and Cu₂Eu₂C₁₈N₄O₄ metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-benzimidazole- 5,6-dicarboxylato ligand (Hbidc). Plenty of hydrogen-bonding and π...π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture.

Original language	English
Pages (from-to)	496-501
Number of pages	6
Journal	Jiegou Huaxue
Volume	30
Issue number	4
State	Published - 15 Apr 2011
Externally published	Yes

Keywords

1H-benzimidazole-5,6-dicarboxylic acid, 3d-4f
Complex
Cu
Eu
Heterometallic

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title = "A lanthanide-transition metal coordination polymer: {[CuEu(Hbidc) 2(H2O)4].H2O}n (H 3bidc = 1hbenzimidazole- 5,6-dicarboxylic acid",

abstract = "The title complex 1, {[CuEu(Hbidc)2(H2O) 4].H2O}n (H3bidc = 1H-benzimidazole- 5,6-dicarboxylic acid), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1, with a = 7.791(2), b = 12.058(3), c = 12.109(3) {\AA}, α = 82.189(5), β = 72.407(5), γ = 89.184(4)̊, V = 1073.7(5) {\AA}3, C18H 18CuEuN4O13, Mr = 713.86, Dc = 2.208 g/cm3, μ(MoKa) = 3.967 mm-1, F(000) = 700, GOOF = 0.950, Z = 2, the final R = 0.0531 and wR = 0.1068 for I > 2σ(I). Complex 1 possess a tape-like chain structure consisting of Eu2C8O4 and Cu2Eu2C18N4O4 metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-benzimidazole- 5,6-dicarboxylato ligand (Hbidc). Plenty of hydrogen-bonding and π...π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture.",

keywords = "1H-benzimidazole-5,6-dicarboxylic acid, 3d-4f, Complex, Cu, Eu, Heterometallic",

author = "Zhou Xin-Hui and Huang Wei",

year = "2011",

month = apr,

day = "15",

language = "英语",

volume = "30",

pages = "496--501",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "4",

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TY - JOUR

T1 - A lanthanide-transition metal coordination polymer

T2 - {[CuEu(Hbidc) 2(H2O)4].H2O}n (H 3bidc = 1hbenzimidazole- 5,6-dicarboxylic acid

AU - Xin-Hui, Zhou

AU - Wei, Huang

PY - 2011/4/15

Y1 - 2011/4/15

N2 - The title complex 1, {[CuEu(Hbidc)2(H2O) 4].H2O}n (H3bidc = 1H-benzimidazole- 5,6-dicarboxylic acid), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1, with a = 7.791(2), b = 12.058(3), c = 12.109(3) Å, α = 82.189(5), β = 72.407(5), γ = 89.184(4)̊, V = 1073.7(5) Å3, C18H 18CuEuN4O13, Mr = 713.86, Dc = 2.208 g/cm3, μ(MoKa) = 3.967 mm-1, F(000) = 700, GOOF = 0.950, Z = 2, the final R = 0.0531 and wR = 0.1068 for I > 2σ(I). Complex 1 possess a tape-like chain structure consisting of Eu2C8O4 and Cu2Eu2C18N4O4 metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-benzimidazole- 5,6-dicarboxylato ligand (Hbidc). Plenty of hydrogen-bonding and π...π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture.

AB - The title complex 1, {[CuEu(Hbidc)2(H2O) 4].H2O}n (H3bidc = 1H-benzimidazole- 5,6-dicarboxylic acid), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1, with a = 7.791(2), b = 12.058(3), c = 12.109(3) Å, α = 82.189(5), β = 72.407(5), γ = 89.184(4)̊, V = 1073.7(5) Å3, C18H 18CuEuN4O13, Mr = 713.86, Dc = 2.208 g/cm3, μ(MoKa) = 3.967 mm-1, F(000) = 700, GOOF = 0.950, Z = 2, the final R = 0.0531 and wR = 0.1068 for I > 2σ(I). Complex 1 possess a tape-like chain structure consisting of Eu2C8O4 and Cu2Eu2C18N4O4 metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-benzimidazole- 5,6-dicarboxylato ligand (Hbidc). Plenty of hydrogen-bonding and π...π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture.

KW - 1H-benzimidazole-5,6-dicarboxylic acid, 3d-4f

KW - Complex

KW - Cu

KW - Eu

KW - Heterometallic

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M3 - 文章

AN - SCOPUS:79955890331

SN - 0254-5861

VL - 30

SP - 496

EP - 501

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 4

ER -

A lanthanide-transition metal coordination polymer: {[CuEu(Hbidc) ₂(H₂O)₄].H₂O}_n (H ₃bidc = 1hbenzimidazole- 5,6-dicarboxylic acid

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