A Composition Design Strategy for Refractory High-Entropy Alloys

How to rationally design composition of alloys with desired properties has always been an open and challenging question, especially for high-entropy alloy (HEA) which has huge selections of composition due to the feature of multi-principal elements. Although great efforts have been made in the past decades, such as approaches based on thermo-kinetic analysis and simulations, strategies to quick determine the optimal HEA composition remain lacking. In this study, based on the effective estimations of elastic modulus of alloys from compositions, we proposed a strategy to design intrinsically strong, ductile, and low-weight refractory HEA (RHEA) compositions. First, the Young’s moduli of three RHEAs were experimentally measured using uniaxial tensile test and impulse excitation of vibration (IEV) test. Then, the present results, combining with the data of elastic moduli of ~130 HEAs in literature, were utilized to validate the prediction of elastic moduli from compositions of HEAs. Finally, based on the property maps that containing 38,326 compositions, a novel RHEA was designed and experimentally tested, exhibiting superior strength, ductility, and low density compared to the equimolar NbMoTaVW alloy. This study provides a new strategy for developing HEAs and contributes to the development of new refractory HEAs with desired properties.